UNIQUE STRUCTURAL FEATURES IN SILVER(I) DITHIOETHER COMPLEXES - THE SINGLE-CRYSTAL STRUCTURES OF [AG-N(PHSCH(2)CH(2)CH(2)SPH)(2N)](BF4)(N)CENTER-DOT-0.5NH(2)O AND[AG-N(MESCH(2)CH(2)CH(2)SME)(N)](BF4)(N)

被引：69

作者：

BLACK, JR ^{[1
]}

CHAMPNESS, NR ^{[1
]}

LEVASON, W ^{[1
]}

REID, G ^{[1
]}

机构：

[1] UNIV SOUTHAMPTON,DEPT CHEM,SOUTHAMPTON SO17 1BJ,HANTS,ENGLAND

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1995年 / 12期

关键词：

D O I：

10.1039/c39950001277

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The X-ray structure of [Ag-n(PhSCH(2)CH(2)CH(2)SPh)(2n)](n+) shows an infinite array of tetrahedral Ag-I atoms coordinated via one S-donor of four distinct PhSCH(2)CH(2)CH(2)SPh ligands, whereas [Ag-n(MeSCH(2)CH(2)CH(2)SMe)(n)](n+) is a chain polymer involving trigonal (mu(2)-S)(2),S ligation with one S-donor bridging two adjacent Agi centres while the other S-donor of the dithioether ligand is non-bridging.

引用

页码：1277 / 1278

页数：2

共 17 条

[1] STRUCTURES OF 3 POLYMERIC COMPLEXES [SILVER(I) NITRATE]X-1,4-OXATHIANE, (AGNO3)X.C4H8OS[X=1(I),2(II),6(III)] [J].

BARNES, JC ;

PATON, JD .

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1984, 40 (JAN) :72-78

[2]

BLACK J, UNPUB

[3] STRUCTURAL ISOMERISM IN SILVER THIOETHER MACROCYCLIC CHEMISTRY - THE SYNTHESIS, REDOX PROPERTIES AND CRYSTAL-STRUCTURES OF [AGN([15]ANES5)N][PF6]N, [AG2([15]ANES5)2][BPH4]2 AND [AG([15]ANES5)][B(C6F5)4] ([15]ANES5=1,4,7,10,13-PENTATHIACYCLOPENTADECANE) [J].

BLAKE, AJ ;

COLLISON, D ;

GOULD, RO ;

REID, G ;

SCHRODER, M .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1993, (04) :521-531

[4] [AG2(1,4,7,10,13-PENTATHIACYCLOPENTADECANE)2]2+ - A BINUCLEAR SILVER(I) COMPLEX INCORPORATING ASYMMETRICALLY BRIDGING THIOETHER DONORS [J].

BLAKE, AJ ;

GOULD, RO ;

REID, G ;

SCHRODER, M .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1990, (14) :974-976

[5] ON THE TRANSPORT AND SELECTIVE COMPLEXATION OF SILVER(I) BY MIXED THIOETHER-OXA CROWNS - THE SINGLE-CRYSTAL X-RAY STRUCTURES OF [AGN([15]ANES2O3)N](PF6)N AND [AG2([15]ANES2O3)3](PF6)2 ([15]ANES2O3 = 1,4,7-TRIOXA-10,13-DITHIACYCLOPENTADECANE) [J].

BLAKE, AJ ;

REID, G ;

SCHRODER, M .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1992, (15) :1074-1076

[6] SILVER THIOETHER CHEMISTRY - SYNTHESIS, X-RAY CRYSTAL-STRUCTURE AND REDOX PROPERTIES OF [AG([18]ANES6)]+ ([18]ANES6=1,4,7,10,13,16-HEXATHIACYCLOOCTADECANE) [J].

BLAKE, AJ ;

GOULD, RO ;

HOLDER, AJ ;

HYDE, TI ;

SCHRODER, M .

POLYHEDRON, 1989, 8 (04) :513-518

[7] SYNTHESIS AND CHARACTERIZATION OF NOVEL MOLYBDENUM(III) CONFACIAL BIOCTAHEDRAL COMPLEXES - X-RAY CRYSTAL-STRUCTURES OF [PH4P][(ME2S)-CL2MO(MU-CL)3MOCL2(SME2)] AND (ME2S)CL2MO(MU-ME2S)(MU-CL)2MOCL2-(SME2) [J].

BOORMAN, PM ;

MOYNIHAN, KJ ;

OAKLEY, RT .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1982, (16) :899-901

[8] THE SYNTHESIS AND CHARACTERIZATION OF MU-HYDRIDO-BIS-(MU-SULPHIDE)-DITUNGSTEN(III) COMPLEXES - THE X-RAY CRYSTAL-STRUCTURE OF [HPPH3][CL3W(MU-H)(MU-ME2S)2WCL3] [J].

BOORMAN, PM ;

MOYNIHAN, KJ ;

KERR, KA .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1981, (24) :1286-1288

[9] CROWN THIOETHER CHEMISTRY - SYNTHESIS AND CHARACTERIZATION OF BIS(1,4,7-TRITHIACYCLONONANE)SILVER(I) TRIFLUOROMETHANESULFONATE, AN OCTAHEDRAL HOMOLEPTIC THIOETHER COMPLEX OF AGI SHOWING UNUSUALLY FACILE OXIDATION [J].

CLARKSON, J ;

YAGBASAN, R ;

BLOWER, PJ ;

RAWLE, SC ;

COOPER, SR .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1987, (12) :950-951

[10] BINUCLEAR CHLORO COMPLEXES OF TANTALUM(III) WITH TANTALUM-TANTALUM DOUBLE-BONDS [J].

COTTON, FA ;

NAJJAR, RC .

INORGANIC CHEMISTRY, 1981, 20 (08) :2716-2719

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