KINETICS OF HOMOGENEOUS CATALYTIC-OXIDATION OF FORMIC-ACID IN THE MEDIUM OF ACETIC-ACID

被引：0
作者：
TARUNIN, BI
TARUNINA, VN
TALINA, EV
机构：
来源：
KINETICS AND CATALYSIS | 1994年 / 35卷 / 05期
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中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The kinetics of formic acid oxidation by ozone in a medium of acetic acid in the presence of Mn(IV) is studied. It is established that the catalytic effect of Mn(IV) on this process is inconsistent with already known mechanisms. A reaction scheme is suggested, which includes the stage of formation of complexes of formic acid with Mn(IV). It is found that the catalytic activity of Mn(IV) in the process studied is lower than that of Co(III).
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页码：668 / 671
页数：4
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