EVIDENCE FOR A (PI-ALLYL)PALLADIUM INTERMEDIATE IN THE QUINONE-BASED PALLADIUM-CATALYZED ALLYLIC ACETOXYLATION

被引：45

作者：

GRENNBERG, H

SIMON, V

BACKVALL, JE

机构：

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1994年 / 03期

关键词：

D O I：

10.1039/c39940000265

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The mechanism of the quinone-based palladium-catalysed allylic acetoxylation of cyclohexene is studied using 1,2-dideuteriocyclohexene (55-70% D) as substrate; the distribution of the deuterium label in the product, determined by H-1 NMR spectroscopy, is that expected for a (pi-allyl)palladium intermediate.

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页码：265 / 266

页数：2

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