PREPARATION OF [HYDROXY(((+)-10-CAMPHORSULFONYL)OXY)IODO]BENZENE AND ITS REACTIVITY TOWARD CARBONYL-COMPOUNDS

被引：84

作者：

HATZIGRIGORIOU, E

VARVOGLIS, A

BAKOLACHRISTIANOPOULOU, M

机构：

[1] Laboratory of Organic Chemistry, University of Thessaloniki

来源：

JOURNAL OF ORGANIC CHEMISTRY | 1990年 / 55卷 / 01期

关键词：

D O I：

10.1021/jo00288a053

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The title compound is prepared and used for the direct a-((10-camphorsulfonyl) oxylation) of various ketones and carbonyl compounds with an active methylene group. Its reaction with 2-butanone and 4-methyl-2-pentanone yields predominantly the corresponding 1-sulfonyloxy derivatives. The stereoselectivity of the reaction is studied by using benzoylacetone, ethyl benzoylacetate, and propiophenone. In some reactions 10-camphorsulfonyl peroxide is formed as a byproduct. © 1990, American Chemical Society. All rights reserved.

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页码：315 / 318

页数：4

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