SYNTHESIS OF SHIKALKIN AND CERTAIN RELATED-COMPOUNDS

被引：6

作者：

NOVIKOV, VL ^{[1
]}

BALANEVA, NN ^{[1
]}

MOISEENKOV, AM ^{[1
]}

ELYAKOV, GB ^{[1
]}

机构：

[1] ND ZELINSKI ORGAN CHEM INST,MOSCOW 117913,RUSSIA

来源：

BULLETIN OF THE RUSSIAN ACADEMY OF SCIENCES-DIVISION OF CHEMICAL SCIENCE | 1992年 / 41卷 / 08期

关键词：

SHIKONIN; ALKANNIN; SHIKALKIN; NAPHTHAZARINE; TETRAMETHOXYNAPHTHALENE; OLEFINIZATION ACCORDING TO WITTIG; CYCLOPROPYL CARBINYLIC REARRANGEMENT; CERIUM AMMONIUM NITRATE;

D O I：

10.1007/BF00864352

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A successful total synthesis of a biologically active pigment from plants of the Boraginaceae family was carried out with naphthazarine as the starting material, and using the 1,4,5,8-tetramethoxynaphthalene, the corresponding 2-vinyl derivative and its epoxide or a cyclopropane adduct with diazoacetic ester at the key stages. In the course of developing the scheme of the synthesis of shikalkin, its three analogs were obtained, differing in the nature of the monoterpenoid side chain.

引用

页码：1485 / 1494

页数：10

共 6 条

[1] A new facile synthesis of shikalkin
Lu, Qun
Tang, Hao Lun
Shao, Yan Qiang
Cai, Jun Chao
CHINESE CHEMICAL LETTERS, 2008, 19 (02) : 172 - 174
[2] New Synthesis of (±)Shikalkin
Hai YANG1
ChineseChemicalLetters, 2002, (06) : 515 - 518
[3] New synthesis of (±)shikalkin
Yang, H
Li, Q
Bao, JX
Lu, W
Aisa, HA
Cai, JC
CHINESE CHEMICAL LETTERS, 2002, 13 (06) : 515 - 518
[4] A new facile synthesis of shikalkin
Qun Lu a
ChineseChemicalLetters, 2008, (02) : 172 - 174
[5] QUINONES AND RELATED COMPOUNDS IN HIGHER-PLANTS .8. BIOSYNTHESIS OF SHIKONIN IN CALLUS-CULTURES OF LITHOSPERMUM-ERYTHRORHIZON
INOUYE, H
UEDA, S
INOUE, K
MATSUMURA, H
PHYTOCHEMISTRY, 1979, 18 (08) : 1301 - 1308
[6] Synthesis of fullerene Γ-lactones by free radical reaction of C60 with ketones promoted by compounds of transition metals Cr(VI), Ce(IV)
R. G. Bulgakov
Z. S. Kinzyabaeva
Russian Journal of Organic Chemistry, 2014, 50 : 1189 - 1193

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