RHODIUM-CATALYZED HYDROFORMYLATION USING SLIM PHOSPHATE LIGANDS TO IMPROVE SELECTIVITY

被引：8
|
作者：
POELSMA, SN [1 ]
MAITLIS, PM [1 ]
机构：
[1] UNIV SHEFFIELD,DEPT CHEM,SHEFFIELD S3 7HF,S YORKSHIRE,ENGLAND
来源：
JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1993年 / 451卷 / 1-2期
关键词：
D O I：
10.1016/0022-328X(93)83038-W
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Catalysts based on [Rh(R1COCHCOR1)(CO)2] and a Phosphite are active for hydroformylation of hex-1-ene under very mild conditions; very bulky phosphites such as (2-tBu-4-MeC6H3O)3P, 3, give much olefin isomerisation, while the slim caged phosphite ligands, P(OCH2)3CR2, show high regioselectivity towards formation of n-C6H13CHO.
引用
收藏
页码：C15 / C17
页数：3
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