RHODIUM-CATALYZED HYDROFORMYLATION USING SLIM PHOSPHATE LIGANDS TO IMPROVE SELECTIVITY

被引：8

作者：

POELSMA, SN ^{[1
]}

MAITLIS, PM ^{[1
]}

机构：

[1] UNIV SHEFFIELD,DEPT CHEM,SHEFFIELD S3 7HF,S YORKSHIRE,ENGLAND

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1993年 / 451卷 / 1-2期

关键词：

D O I：

10.1016/0022-328X(93)83038-W

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Catalysts based on [Rh(R1COCHCOR1)(CO)2] and a Phosphite are active for hydroformylation of hex-1-ene under very mild conditions; very bulky phosphites such as (2-tBu-4-MeC6H3O)3P, 3, give much olefin isomerisation, while the slim caged phosphite ligands, P(OCH2)3CR2, show high regioselectivity towards formation of n-C6H13CHO.

引用

页码：C15 / C17

页数：3

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