LIGAND SUBSTITUTION PATTERNS CONTROL PHOTOPHYSICAL PROPERTIES OF RUTHENIUM(II)-2,2',/6',2''-TERPYRIDINE COMPLEXES - ROOM-TEMPERATURE EMISSION FROM [RU(TPY)2]2+ ANALOGS

被引：67
|
作者：
CONSTABLE, EC [1 ]
THOMPSON, AMWC [1 ]
ARMAROLI, N [1 ]
BALZANI, V [1 ]
MAESTRI, M [1 ]
机构：
[1] UNIV BOLOGNA,DIPARTIMENTO CHIM G CIAMICIAN,I-40126 BOLOGNA,ITALY
来源：
POLYHEDRON | 1992年 / 11卷 / 20期
关键词：
D O I：
10.1016/S0277-5387(00)80243-0
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Ruthenium(II) complexes of 2,2' : 6',2"-terpyridine have not been widely investigated as photocatalysts; the introduction of electron-withdrawing substituents into the 4'-position of the ligand results in complexes [Ru(Xtpy)2]2+ (Xtpy = Cltpy or MeSO2tpy), which luminesce in fluid solution at room temperature.
引用
收藏
页码：2707 / 2709
页数：3
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