VIBRATION ROTATION BANDS OF 15N218O EFFECTS OF FERMI RESONANCE AND 1-TYPE DOUBLING

被引：22

作者：

MANTZ, AW

RAO, KN

JONES, JH

POTTER, RM

机构：

[1] Laboratory of Molecular Spectroscopy and Infrared Studies, Department of Physics, The Ohio State University, Columbus

[2] Los Alamos Scientific Laboratory, University of California, Los Alamos

来源：

JOURNAL OF MOLECULAR SPECTROSCOPY | 1969年 / 30卷 / 03期

关键词：

D O I：

10.1016/0022-2852(69)90283-5

中图分类号：

O64 [物理化学（理论化学）、化学物理学]; O56 [分子物理学、原子物理学];

学科分类号：

070203 ; 070304 ; 081704 ; 1406 ;

摘要：

The rotational structure in twenty vibration rotation bands of 15N218O observed between 1080 and 4910 cm-1, has been measured and analyzed. In view of the improved resolution available, it has been possible to resolve many more l-type doublets than before. Three Fermi diads were measured, and from these data it was possible to establish an average value for the Fermi interaction parameter, k122 = 32.3 cm-1. Isotopic impurity bands due to 15N216O, 15N14N18O, 14N15N18O, and 15N217O were identified. An experimental value of the rotational constant for the ground vibrational state of 15N217O as B0000 = 0.39276 ± 0.00003 cm-1 was determined. © 1969.

引用

页码：513 / &

共 5 条

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