PHOTOCYCLIZATION OF ENAMIDES .29. DEHYDROGENATION WITH BENZENESELENINIC ANHYDRIDE IN THE TOTAL SYNTHESIS OF ERGOT ALKALOIDS

被引：26

作者：

NINOMIYA, I ^{[1
]}

HASHIMOTO, C ^{[1
]}

KIGUCHI, T ^{[1
]}

NAITO, T ^{[1
]}

BARTON, DHR ^{[1
]}

LUSINCHI, X ^{[1
]}

MILLIET, P ^{[1
]}

机构：

[1] CNRS,INST CHIM SUBST NAT,F-91198 GIF SUR YVETTE,FRANCE

来源：

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1 | 1990年 / 03期

关键词：

D O I：

10.1039/p19900000707

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Investigation of the dehydrogenative conversion of indolines into indoles with benzeneseleninic anhydride (1) resulted in the development of an efficient standardised procedure, which was successfully applied to the final steps in first total synthesis of (±)-lysergol (18), (±)-isolysergol (27), and (±)-elymoclavine (29).

引用

页码：707 / 713

页数：7