LEWIS-BASE ADDUCTS OF MAIN GROUP-1 METAL-COMPOUNDS .12. SYNTHESIS AND CRYSTAL-STRUCTURE OF (2,2'-BIPYRIDINE)(BROMO)(PROPAN-2-OL)LITHIUM(I)

被引：3
|
作者：
SKELTON, BW
WHITAKER, CR
WHITE, AH
机构：
[1] Department of Physical and Inorganic Chemistry, University of Western Australia, Nedlands, WA
来源：
AUSTRALIAN JOURNAL OF CHEMISTRY | 1990年 / 43卷 / 04期
关键词：
D O I：
10.1071/CH9900755
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The title compound is readily crystallized from a 1:1 mixture of 2, 2'-bipyridine and lithium(1) bromide in propan-2-ol; its structure has been established by single-crystal X-ray methods at c. 295 K. Crystals are monoclinic, P21/c, a 10·942(3), b 15·060(4), c 9·359(3) Å, β 108·57(2)°, Z = 4; R was 0·050 for 1820 ‘observed’ reflections. In the four-coordinate LiBrN2O environment, Li-Br, 0 are 2-47(1), 1·94(1) Å, and Li-N are 2-05(1), 2-07(1) Å. © 1990 ASEG.
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页码：755 / 758
页数：4
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