THE COMPOUND SODIUM PHENOXIDE-CENTER-DOT-2 PHENOL IN THE SYSTEM OF ITS COMPONENTS

被引：10

作者：

JORCHEL, P ^{[1
]}

SIELER, J ^{[1
]}

机构：

[1] UNIV LEIPZIG,INST ANORGAN CHEM,D-04103 LEIPZIG,GERMANY

来源：

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 1995年 / 621卷 / 06期

关键词：

SODIUM PHENOXIDE 2PHENOL; CRYSTAL STRUCTURE; SYSTEM SODIUM PHENOXIDE PHENOL;

D O I：

10.1002/zaac.19956210628

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

In the whole system of sodiumphenoxide/ phenol the substance sodium phenoxide . 2 phenol is found to be the only compound between the two components. Single crystalls could be obtained by using the growing method according to Bridgman-Stockbarger. The crystal structure of PhONa . 2PhOH contains two different chains. In both of them sodium is coordinated in form of a distorted tetrahedron; in the first one by 4 oxygen, in the second one by 3 oxygen atoms and a phenoxid molecule, which is linked to sodium via its pi-electrons. In the result of this realizations conclusions concerning the Kolbe-Schmitt-Synthesis are possible.

引用

页码：1058 / 1062

页数：5

共 24 条

[21] Na/V/P/N(C2H5)(3)/H2O system at 473 K and the new open framework structure of the vanadium phosphate phase Na-v[((V4-w4+V1+w5+)O-9)(PO4)(2)]center dot(PO4)(x)center dot(OH)(y)center dot zH(2)O (with v=2.8 to 4.0, w=-0.1 to 1.1, x=0 to 0.2, y=0 to 2.1, and z=7 to 10)
Schindler, M
Joswig, W
Baur, WH
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 1997, 623 (01): : 45 - 54
[22] CRYSTAL-STRUCTURE OF NA3(NH4)12[MO57FE6(NO)6O174(OH)3(H2O)24]CENTER-DOT-76H2O, A COMPOUND WITH AN UNIQUE CLUSTER ANION
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BEUGHOLT, C
BERGMANN, U
MONATSHEFTE FUR CHEMIE, 1994, 125 (05): : 525 - 533
[23] The preparation of (BEDO-TTF)(2)Cl center dot 3H2O salt in Bu(4)NHgX(3)+Bu(4)NX+1,2-dichloroethane system. Shubnikov-de Haas oscillations
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SYNTHETIC METALS, 1996, 83 (01) : 7 - 11
[24] Stabilization of a Y-shaped Cu-I coordination in [CuPt2(PPh(3))(5)(mu(3)-S)(2)]PF6 by Pt-2 (PPh(3))(4)(mu-S)(2) and its expansion to a pentanuclear aggregate[Cu{Pt-2(PPh(3))(4)(mu(3)-S)(2)}(2)] PF6 center dot X-ray crystal structure of [CuPt2(PPh(3))(5)(mu(3)-S)(2)]PF6
Liu, H
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POLYHEDRON, 1997, 16 (03) : 377 - 382

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