THE COMPOUND SODIUM PHENOXIDE-CENTER-DOT-2 PHENOL IN THE SYSTEM OF ITS COMPONENTS

被引：10
|
作者：
JORCHEL, P [1 ]
SIELER, J [1 ]
机构：
[1] UNIV LEIPZIG,INST ANORGAN CHEM,D-04103 LEIPZIG,GERMANY
来源：
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 1995年 / 621卷 / 06期
关键词：
SODIUM PHENOXIDE 2PHENOL; CRYSTAL STRUCTURE; SYSTEM SODIUM PHENOXIDE PHENOL;
D O I：
10.1002/zaac.19956210628
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
In the whole system of sodiumphenoxide/ phenol the substance sodium phenoxide . 2 phenol is found to be the only compound between the two components. Single crystalls could be obtained by using the growing method according to Bridgman-Stockbarger. The crystal structure of PhONa . 2PhOH contains two different chains. In both of them sodium is coordinated in form of a distorted tetrahedron; in the first one by 4 oxygen, in the second one by 3 oxygen atoms and a phenoxid molecule, which is linked to sodium via its pi-electrons. In the result of this realizations conclusions concerning the Kolbe-Schmitt-Synthesis are possible.
引用
收藏
页码：1058 / 1062
页数：5
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