THE COMPOUND SODIUM PHENOXIDE-CENTER-DOT-2 PHENOL IN THE SYSTEM OF ITS COMPONENTS

被引：10

作者：

JORCHEL, P ^{[1
]}

SIELER, J ^{[1
]}

机构：

[1] UNIV LEIPZIG,INST ANORGAN CHEM,D-04103 LEIPZIG,GERMANY

来源：

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 1995年 / 621卷 / 06期

关键词：

SODIUM PHENOXIDE 2PHENOL; CRYSTAL STRUCTURE; SYSTEM SODIUM PHENOXIDE PHENOL;

D O I：

10.1002/zaac.19956210628

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

In the whole system of sodiumphenoxide/ phenol the substance sodium phenoxide . 2 phenol is found to be the only compound between the two components. Single crystalls could be obtained by using the growing method according to Bridgman-Stockbarger. The crystal structure of PhONa . 2PhOH contains two different chains. In both of them sodium is coordinated in form of a distorted tetrahedron; in the first one by 4 oxygen, in the second one by 3 oxygen atoms and a phenoxid molecule, which is linked to sodium via its pi-electrons. In the result of this realizations conclusions concerning the Kolbe-Schmitt-Synthesis are possible.

引用

页码：1058 / 1062

页数：5

共 24 条

[1] Cu(C2N4H4)(2)Br-2 center dot 2H(2)O: an antiferromagnetic cyanoguanidine coordination compound and its characterization
Zhang, Jing
Corkett, Alex J.
van Leusen, Jan
Nelson, Ryky
Dronskowski, Richard
ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES, 2022, 77 (06): : 411 - 417
[2] Crystal structure of the coordination compound of triiodidomethyltin(IV) with 2,2 '-bipyridine, MeSnI3 center dot bipy
Reuter, Hans
Reichelt, Martin
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2016, 72 : 17 - +
[3] Low-temperature crystal structure of the inclusion compound {[N(CH3)(4)](+)(Cl)(2)(-)}center dot CH3CN center dot H2O
Minkwitz, R
Brochler, R
Preut, H
ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES, 1996, 51 (04): : 599 - 601
[4] Interactions in molecular crystals .118. The sodium(benzo-15-crown-5) salt of 2,6-di(tert-butyl)-4-methylphenol, a sodium phenolate with an extremely short Na+center dot center dot center dot O- distance: Structure and density functional calculations
Bock, H
Dienelt, R
Nather, C
Havlas, Z
CHEMISCHE BERICHTE-RECUEIL, 1997, 130 (10): : 1533 - 1537
[5] CRYSTAL-STRUCTURE AND HYDROTHERMAL SYNTHESIS OF THE LAYERED COMPOUND BE-2(PO4)(OH)CENTER-DOT-2H2O
ROBL, C
GOBNER, V
ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES, 1994, 49 (11): : 1499 - 1502
[6] ALKALI-METAL FORMATES .5. THE CRYSTAL-STRUCTURE OF SODIUM FORMATE DIHYDRATE, NAHCO2-CENTER-DOT-2H2O
MULLER, K
RANGE, KJ
HEYNS, AM
ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES, 1994, 49 (09): : 1179 - 1182
[7] THE CRYSTAL-STRUCTURE OF THE SODIUM OXOHYDROXOALUMINATE HYDRATE NA-2[AL2O3(OH)(2)]CENTER-DOT-1.5H(2)O
WEINBERGER, M
SCHNEIDER, M
MULLER, D
GESSNER, W
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 1995, 621 (04): : 679 - 684
[8] STRUCTURE OF HUMAN FACTOR-D A COMPLEMENT-SYSTEM PROTEIN AT 2-CENTER-DOT-0-ANGSTROM RESOLUTION
NARAYANA, SVL
CARSON, M
ELKABBANI, O
KILPATRICK, JM
MOORE, D
CHEN, X
BUGG, CE
VOLANAKIS, JE
DELUCAS, LJ
JOURNAL OF MOLECULAR BIOLOGY, 1994, 235 (02) : 695 - 708
[9] Molecular structure and hydrogen bonding of 4-dimethylaminopyridinioacetate in its crystalline dihydrate and hydrochloride trihydrate, L center dot 2H(2)O and [L(2)H]Cl center dot 3H(2)O (L=p-Me(2)NC(5)H(4)N(+)CH(2)CO(2)(-))
Wei, PR
Li, Q
Mak, TCW
JOURNAL OF CHEMICAL CRYSTALLOGRAPHY, 1996, 26 (02) : 133 - 139
[10] CRYSTAL-STRUCTURE AND THERMAL-DECOMPOSITION OF THE COQUIMBITE-TYPE COMPOUND FE-2(SEO4)(3) CENTER-DOT 9H(2)O
GIESTER, G
MILETICH, R
NEUES JAHRBUCH FUR MINERALOGIE-MONATSHEFTE, 1995, (05): : 211 - 223

← 1 2 3 →