THE COMPOUND SODIUM PHENOXIDE-CENTER-DOT-2 PHENOL IN THE SYSTEM OF ITS COMPONENTS

被引：10

作者：

JORCHEL, P ^{[1
]}

SIELER, J ^{[1
]}

机构：

[1] UNIV LEIPZIG,INST ANORGAN CHEM,D-04103 LEIPZIG,GERMANY

来源：

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 1995年 / 621卷 / 06期

关键词：

SODIUM PHENOXIDE 2PHENOL; CRYSTAL STRUCTURE; SYSTEM SODIUM PHENOXIDE PHENOL;

D O I：

10.1002/zaac.19956210628

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

In the whole system of sodiumphenoxide/ phenol the substance sodium phenoxide . 2 phenol is found to be the only compound between the two components. Single crystalls could be obtained by using the growing method according to Bridgman-Stockbarger. The crystal structure of PhONa . 2PhOH contains two different chains. In both of them sodium is coordinated in form of a distorted tetrahedron; in the first one by 4 oxygen, in the second one by 3 oxygen atoms and a phenoxid molecule, which is linked to sodium via its pi-electrons. In the result of this realizations conclusions concerning the Kolbe-Schmitt-Synthesis are possible.

引用

页码：1058 / 1062

页数：5

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