SYNTHESIS AND X-RAY CRYSTAL-STRUCTURE OF [EU(ETA-6-C6ME6)(ALCL4)2]4 - THE 1ST CYCLOTETRAMERIC LANTHANIDE(II) COMPLEX WITH A NEUTRAL PI-LIGAND

被引：39

作者：

LIANG, HZ ^{[1
]}

SHEN, Q ^{[1
]}

JIN, SC ^{[1
]}

LIN, YH ^{[1
]}

机构：

[1] ACAD SINICA,CHANGCHUN INST APPL CHEM,CHANGCHUN 130022,PEOPLES R CHINA

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1992年 / 06期

关键词：

D O I：

10.1039/c39920000480

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The reaction of EuCl3, AlCl3 and C6Me6 in toluene gives the Eu(II) complex [Eu(eta-6-C6Me6)(AlCl4)2]4; X-ray crystal determination shows the molecule to be a cyclotetramer, in which the four Eu(C6Me6)AlCl4 units are connected via four groups of eta-2-AlCl4.

引用

页码：480 / 481

页数：2

共 8 条

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