ON THE REACTION OF N-(DIPHENYLPHOSPHINYL)-1-PHENYLETHANIMINE WITH AROMATIC-ALDEHYDES GIVING 4-ARYL-2,6-DIPHENYLPYRIDINE DERIVATIVES

被引：44

作者：

KOBAYASHI, T

KAKIUCHI, H

KATO, H

机构：

来源：

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN | 1991年 / 64卷 / 02期

关键词：

D O I：

10.1246/bcsj.64.392

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

N-(Diphenylphosphinyl)-2-phenyl-1-azaallyl anion (1), generated from N-(diphenylphosphinyl)-1-phenylethanimine, reacted with aromatic aldehydes in a 2:1 molar ratio to give 4-aryl-2,6-diphenylpyridines in moderate yields. The intervention of N-phosphinyl-1-azadiene intermediates is proposed on the basis of the independent synthesis of an N-phosphinyl-1-azadiene and its conversion into a pyridine by the reaction with 1.

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页码：392 / 395

页数：4

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