ACETYLENE COMPLEXES OF TITANOCENE AS STARTING MATERIAL FOR 5-MEMBERED TITANACYCLES

被引：39
作者：
ALT, HG
HERRMANN, GS
机构：
[1] Laboratorium für Anorganische Chemie der Universität Bayreuth, D-8580 Bayreuth
来源：
JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1990年 / 390卷 / 02期
关键词：
D O I：
10.1016/0022-328X(90)85028-W
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Die Acetylenkomplexe Cp2Ti(PMe3)(C2H2) und Cp2Ti(C2Me2) reagieren mit Kohlendioxid, Aceton, Acetaldehyd und Ethylen zu fünfgliedrigen Metallacyclen. Der Titanacyclopenten-Komplex Cp2Ti(HCCHCH2CH2] reagiert mit Wasser zum μ-oxo-Komplex [Cp2Ti(CH2CH2CHCH2)]2O. © 1990.
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页码：159 / 169
页数：11
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