SYNTHESIS OF M(0)(ETA(2)-DPPF)2 (M=PD, PT, DPPF=FE(C5H4PPH2)2) AND THEIR REACTIONS WITH FE3(MU(3)-S)2(CO)9 AND ELEMENTAL SULFUR

被引：19

作者：

FANG, ZG ^{[1
]}

LOW, PMN ^{[1
]}

NG, SC ^{[1
]}

HOR, TSA ^{[1
]}

机构：

[1] NATL UNIV SINGAPORE,FAC SCI,DEPT CHEM,SINGAPORE 0511,SINGAPORE

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1994年 / 483卷 / 1-2期

关键词：

PALLADIUM; PLATINUM; DIPHOSPHINE; FERROCENYL PHOSPHINE; SULFUR; CLUSTER;

D O I：

10.1016/0022-328X(94)87141-8

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Reduction of MCl2(eta2-dppf) with NaBH4 gives M(eta2-dppf)2 (M = Pt, 1, Pd, 2). Oxidation of 1 or 2 with S8 gives the tetrasulfido complex M(eta2-S4)(eta2-S4)(eta2-dppf). Addition of 1 or 2 to Fe3(mu3-S)2(CO)9 results in the heterometallic complex (CO)6Fe2(mu3-S)2M(eta2-dppf) (M = Pt, 5; Pd, 6) and two substitution side products Fe3(mu3-S)2(CO)7(mu-dppf) (7) and [Fe3(mu3-S)2(CO)8](mu-dppf) (8).

引用

页码：17 / 20

页数：4

共 69 条

[51] FLUORIDE-ASSISTED REDUCTION OF PALLADIUM(II) PHOSPHINE COMPLEXES [J].

MASON, MR ;

VERKADE, JG .

ORGANOMETALLICS, 1990, 9 (03) :864-865

[52] FLUORIDE-INDUCED REDUCTION OF PALLADIUM(II) AND PLATINUM(II) PHOSPHINE COMPLEXES [J].

MASON, MR ;

VERKADE, JG .

ORGANOMETALLICS, 1992, 11 (06) :2212-2220

[53] THE CONTRASTING ROLES OF THE VARIOUS CHALCOGENS IN THE SYNTHESIS OF MIXED METAL-COMPLEXES (CO)6FE2(MU-3-E)2M(PPH3)2 (E = TE, SE, S, M = NI, PD, PT)) [J].

MATHUR, P ;

MAVUNKAL, IJ ;

RUGMINI, V .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1989, 367 (1-2) :243-248

[54] NITRATO DISPLACEMENT IN [AG-2(NO3)(2)(MU-DPPF)(2)] - MOLECULAR-STRUCTURE OF A HOMOLEPTIC DPPF COMPLEX, [AG-2(MU-DPPF)(DPPF)(2)](PF6)(2) (DPPF=1,1'-BIS(DIPHENYLPHOSPHINO)FERROCENE) [J].

NEO, SP ;

HOR, TSA ;

ZHOU, ZY ;

MAK, CW .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1994, 464 (01) :113-119

[55] CATALYTIC ASYMMETRIC ARYLATION OF 2,3-DIHYDROFURAN WITH ARYL TRIFLATES [J].

OZAWA, F ;

KUBO, A ;

HAYASHI, T .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1991, 113 (04) :1417-1419

[56]

PHANG LT, 1994, J ORGANOMET CHEM, V469, P253

[57] SUBSTITUTED METAL-CARBONYLS .21. [M(CO)5(DPPF-P)] [M = CR, MO OR W - DPPF = FE(C5H4PPH2)2] AS A METALLOLIGAND IN HETEROPOLYMETALLIC AGGREGATES OF AU-I, PD-II AND PT-II - CRYSTAL AND MOLECULAR-STRUCTURES OF [PTCL2(MU-DPPF)W(CO)5)2] AND [MO(CO)5(DPPF-P)] [J].

PHANG, LT ;

AUYEUNG, SCF ;

HOR, TSA ;

KHOO, SB ;

ZHOU, ZY ;

MAK, TCW .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1993, (01) :165-172

[58] REACTIONS OF PERFLUOROMETHYL-SUBSTITUTED CYCLOPOLYPHOSPHINES WITH ZEROVALENT GROUP-10 METAL-COMPLEXES - CRYSTAL AND MOLECULAR-STRUCTURE OF A COMPLEX WITH A COORDINATED DIPHOSPHENE, [PD(ETA-2-CF3P=PCF3)(PPH3)2] [J].

PHILLIPS, IG ;

BALL, RG ;

CAVELL, RG .

INORGANIC CHEMISTRY, 1992, 31 (09) :1633-1641

[59] SYNTHESIS AND SOLUTION STATE OF ((MU-DPPF)(CU(DPPF))2)X2 (DPPF=1,1'-BIS(DIPHENYLPHOSPHINO)FERROCENE - X = CLO4-, BF4-) [J].

PILLONI, G ;

GRAZIANI, R ;

LONGATO, B ;

CORAIN, B .

INORGANICA CHIMICA ACTA, 1991, 190 (02) :165-167

[60] HETEROBIMETALLIC COMPLEXES VIA ETA-1-PH2PCH2PPH2 COMPLEXES OF PLATINUM OR PALLADIUM DICYANIDES [J].

PRINGLE, PG ;

SHAW, BL .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1982, (16) :956-957

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