SYNTHESIS OF M(0)(ETA(2)-DPPF)2 (M=PD, PT, DPPF=FE(C5H4PPH2)2) AND THEIR REACTIONS WITH FE3(MU(3)-S)2(CO)9 AND ELEMENTAL SULFUR

被引：19

作者：

FANG, ZG ^{[1
]}

LOW, PMN ^{[1
]}

NG, SC ^{[1
]}

HOR, TSA ^{[1
]}

机构：

[1] NATL UNIV SINGAPORE,FAC SCI,DEPT CHEM,SINGAPORE 0511,SINGAPORE

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1994年 / 483卷 / 1-2期

关键词：

PALLADIUM; PLATINUM; DIPHOSPHINE; FERROCENYL PHOSPHINE; SULFUR; CLUSTER;

D O I：

10.1016/0022-328X(94)87141-8

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Reduction of MCl2(eta2-dppf) with NaBH4 gives M(eta2-dppf)2 (M = Pt, 1, Pd, 2). Oxidation of 1 or 2 with S8 gives the tetrasulfido complex M(eta2-S4)(eta2-S4)(eta2-dppf). Addition of 1 or 2 to Fe3(mu3-S)2(CO)9 results in the heterometallic complex (CO)6Fe2(mu3-S)2M(eta2-dppf) (M = Pt, 5; Pd, 6) and two substitution side products Fe3(mu3-S)2(CO)7(mu-dppf) (7) and [Fe3(mu3-S)2(CO)8](mu-dppf) (8).

引用

页码：17 / 20

页数：4

共 69 条

[1] LIGAND SUBSTITUTION VS LIGAND ADDITION .1. DIFFERENCES IN REACTIVITY BETWEEN 1ST-ROW AND 3RD-ROW TRANSITION-METAL CLUSTERS - REACTIONS OF DIMETHYLAMINE WITH THE SULFIDOMETAL CARBONYL CLUSTERS FE3(CO)9(MU-3-S)2, OS3(CO)9(MU-3-S)2 [J].

ADAMS, RD ;

BABIN, JE .

INORGANIC CHEMISTRY, 1986, 25 (19) :3418-3422

[2] CLUSTER SYNTHESIS .11. ROLE OF SULFIDO LIGANDS IN THE SYNTHESIS OF HETERONUCLEAR CLUSTERS - SYNTHESIS AND CRYSTAL AND MOLECULAR-STRUCTURES OF PTOS4(CO)11(PME2PH)2(MU3-S)2 AND PTOS3(CO)9(PME2PH)2(MU3-S)2 [J].

ADAMS, RD ;

HORVATH, IT ;

WANG, S .

INORGANIC CHEMISTRY, 1986, 25 (10) :1617-1623

[3] CLUSTER SYNTHESIS .8. SYNTHESIS AND CRYSTAL AND MOLECULAR-STRUCTURES OF THE SULFIDO-BRIDGED PLATINUM OSMIUM CARBONYL CLUSTER COMPOUNDS PTOS3(CO)9L(PPH3)(MU-3-S)2 (L=CO, PPH3) [J].

ADAMS, RD ;

HOR, TSA ;

HORVATH, IT .

INORGANIC CHEMISTRY, 1984, 23 (26) :4733-4738

[4] SELECTIVE PHASE-TRANSFER AND PALLADIUM(O)-CATALYZED CARBONYLATION, CARBALKOXYLATION, AND REDUCTION REACTIONS [J].

ALPER, H ;

HASHEM, K ;

HEVELING, J .

ORGANOMETALLICS, 1982, 1 (06) :775-778

[5] CRYSTAL AND MOLECULAR-STRUCTURE OF BIS[1,3-BIS(DIPHENYLPHOSPHINO)PROPANE]PLATINUM(0) - A REEVALUATION [J].

ASKER, KA ;

HITCHCOCK, PB ;

MOULDING, RP ;

SEDDON, KR .

INORGANIC CHEMISTRY, 1990, 29 (20) :4146-4148

[6] 1,1' BIS(DIPHENYLPHOSPHINO)FERROCENE COMPLEXES OF PLATINUM(II) AND PLATINUM(I) - CRYSTAL AND MOLECULAR-STRUCTURE OF [(FE(ETA-5-C5H4PPH2)PT(MU-H)(MU-CO)PT(FE(ETA-5-C5H4PPH2)2)][BF4]-0.5H2O [J].

BANDINI, AL ;

BANDITELLI, G ;

CINELLU, MA ;

SANNA, G ;

MINGHETTI, G ;

DEMARTIN, F ;

MANASSERO, M .

INORGANIC CHEMISTRY, 1989, 28 (03) :404-410

[7]

BARNARD CFJ, 1987, COMPREHENSIVE ORGANO, V5, P1101

[8] SYMMETRICALLY DISUBSTITUTED FERROCENES .1. SYNTHESIS OF POTENTIAL BIDENTATE LIGANDS [J].

BISHOP, JJ ;

DAVISON, A ;

KATCHER, ML ;

LICHTENB.DW ;

MERRILL, RE ;

SMART, JC .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1971, 27 (02) :241-&

[9] CARBONYLMETALATE-INDUCED PHOSPHORUS MIGRATION AND PH2PCH2PPH2-(DPPM-) ASSISTED SYNTHESIS OF BIMETALLIC COMPLEXES AND CLUSTERS OF PD AND PT WITH MO, W, MN, AND CO [J].

BRAUNSTEIN, P ;

DEBELLEFON, CD ;

OSWALD, B .

INORGANIC CHEMISTRY, 1993, 32 (09) :1649-1655

[10] SYNTHESIS AND REACTIVITY OF BIS(DIPHENYLPHOSPHINO)METHANE-(DPPM)-BRIDGED PD-MO AND PD-W COMPLEXES - CRYSTAL-STRUCTURE OF [PD(MU-CO)(MU-DPPM)2MO(CP)(CO)][PF6] (CP = ETA-5-C5H5) [J].

BRAUNSTEIN, P ;

OSWALD, B ;

DECIAN, A ;

FISCHER, J .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1991, (10) :2685-2692

← 1 2 3 4 5 6 7 →