N'-(2,4-Dinitrophenyl)acetohydrazide monohydrate

被引:0
|
作者
Essid, Manel [1 ]
Marouani, Houda [1 ]
Ai-Deyab, Salem S. [2 ]
Rzaigui, Mohamed [1 ]
机构
[1] Fac Sci Bizerte, Lab Chim Mat, Zarzouna 7021, Tunisia
[2] King Saud Univ, Fac Sci, Chem Dept, Riyadh 11451, Saudi Arabia
来源
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2013年 / 69卷
关键词
data-to-parameter ratio = 29.9; meanω(C - C) = 0.003 A °; Rfactor = 0.071; single-crystal X-ray study; T = 293 K; wRfactor = 0.195;
D O I
10.1107/S1600536813018916
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
In the crystal structure of the title compound, C8H8N4O5 center dot H2O, the organic and lattice water molecules are linked together via N-H center dot center dot center dot O and O-H center dot center dot center dot O hydrogen bonds. A C-H center dot center dot center dot O interaction is also observed between the organic molecules. These hydrogen bonds and interactions lead to the formation of a three-dimensional network. An intramolecular N-H center dot center dot center dot O hydrogen bond also occurs. The dihedral angle between the acetyl group and the almost planar hydrazide moiety [maximum deviation from the least-squares plane is 0.209 (2) angstrom for one of the nitro O atoms] is 88.5 (3)degrees.
引用
收藏
页码:O1249 / +
页数:6
相关论文
共 50 条
  • [1] N′-(2,4-Dinitrophenyl)acetohydrazide
    Zia-ur-Rehman, Muhammad
    Elsegood, Mark R. J.
    Mahmud, Shahid
    Siddiqui, Hamid Latif
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2008, 64 : O1441 - U1812
  • [2] N'-( 2,4-Dinitrophenyl) benzohydrazide
    Saeed, Aamer
    Arshad, Ifzan
    Floerke, Ulrich
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2012, 68 : 02418 - +
  • [3] [(2,4-Dinitrophenyl)hydrazono](phenyl)-acetaldehyde oxime monohydrate
    Zulfikaroglu, Aysin
    Bati, Humeyra
    Caliskan, Nezihe
    Yuksektepe, Cigdem
    Buyukgungor, Orhan
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2007, 63 : O582 - O584
  • [4] N-(2,4-dinitrophenyl)dehydroabietylamine
    Qiu, Fei
    Hong, Min
    Jiang, Dawei
    Zhu, Jin
    Huang, Lequn Lee
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2008, 64 : O889 - U2354
  • [5] ON N-(2,4-DINITROPHENYL) PHTHALIMIDE
    BECKWITH, AL
    MILLER, J
    AUSTRALIAN JOURNAL OF SCIENTIFIC RESEARCH SERIES A-PHYSICAL SCIENCES, 1952, 5 (04): : 786 - 789
  • [6] 2,4-DINITROPHENYL PHOSPHATE
    KIRBY, AJ
    VARVOGLI.AG
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1966, 88 (08) : 1823 - &
  • [7] N-Cycloheptylidene-N′-(2,4-dinitrophenyl)hydrazine
    Kia, Reza
    Fun, Hoong-Kun
    Kargar, Hadi
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2009, 65 : O382 - U2686
  • [8] S-]N AND N-]S REVERSE REARRANGEMENT OF S-(2,4-DINITROPHENYL)CYSTEINES AND N-(2,4-DINITROPHENYL)CYSTEINES
    KONDO, H
    MORIUCHI, F
    SUNAMOTO, J
    JOURNAL OF ORGANIC CHEMISTRY, 1981, 46 (07): : 1333 - 1336
  • [9] REACTIONS OF METHYL-ESTERS OF N-(2,4-DINITROPHENYL)-GLYCINE AND N-METHYL-N-(2,4-DINITROPHENYL)GLYCINE WITH SODIUM METHOXIDE
    MACHACEK, V
    STERBA, V
    KOLB, I
    LYCKA, A
    COLLECTION OF CZECHOSLOVAK CHEMICAL COMMUNICATIONS, 1988, 53 (05) : 1044 - 1052
  • [10] N-[(E)-( 2,4-dinitrophenyl)methylene]aniline
    Barys, M
    Ciunik, Z
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2005, 61 : O1967 - O1969