RADICAL ADDITIONS OF TERTIARY-AMINES TO CHLOROTRIFLUOROETHYLENE

被引：4

作者：

BARTA, M

HAMPL, F

LISKA, F

DEDEK, V

机构：

来源：

COLLECTION OF CZECHOSLOVAK CHEMICAL COMMUNICATIONS | 1994年 / 59卷 / 08期

关键词：

D O I：

10.1135/cccc19941820

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Radical addition of ethyldimethylamine, cyclohexyldimethylamine, 1-methylpyrrolidine, 1-methyl-piperidine, 1-methylperhydroazepine and 1-methylmorpholine to chlorotrifluoroethylene afforded 1 : 1 and 1 : 2 adducts containing 2-chloro-1,1,2-trifluoroethyl groups in the alpha- or alpha,alpha'-positions. Further reaction products were 1 : 2 telomers and secondary products arising by reduction of the chlorine atom in CHFCl groups by tertiary amines. The reaction course and mass and NMR spectra of the products are discussed.

引用

页码：1820 / 1832

页数：13

共 9 条

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Clarke H. T., 1933, J AM CHEM SOC, V55, P4571, DOI 10.1021/ja01338a041

[2]

DEDEK V, 1969, COLLECT CZECH CHEM C, V34, P3769

[3] FREE-RADICAL REARRANGEMENTS IN TELOMERIZATION [J].