DIFLUOROIODOMETHANE - PRACTICAL SYNTHESIS AND REACTION WITH ALKENES

被引：58

作者：

CAO, P ^{[1
]}

DUAN, JX ^{[1
]}

CHEN, QY ^{[1
]}

机构：

[1] ACAD SINICA,SHANGHAI INST ORGAN CHEM,345 LINGLING LU,SHANGHAI 200032,PEOPLES R CHINA

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1994年 / 06期

关键词：

D O I：

10.1039/c39940000737

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Difluorocarbene precusors 2, FSO2CF2COF, FSO2CF2CO2H, FSO2CF2CO2Me and XCF2CO2M react with KI to give HCF2I 1 in high yields; a smooth reaction of 1 with alkenes or alkynes in the presence of Na2S2O4 gives the difluoromethylated adducts in good yields.

引用

页码：737 / 738

页数：2

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