MOLECULAR AND CRYSTAL-STRUCTURE OF BIS(ETA(5)-CYCLOPENTADIENYL)TITANIUM(IV) DIBROMIDE, TI(ETA(5)-C5H5)2BR2

被引：12

作者：

KLOURAS, N ^{[1
]}

NASTOPOULOS, V ^{[1
]}

DEMAKOPOULOS, I ^{[1
]}

LEBAN, I ^{[1
]}

机构：

[1] UNIV LJUBLJANA,DEPT CHEM & CHEM TECHNOL,LJUBLJANA,SLOVENIA

来源：

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 1993年 / 619卷 / 11期

关键词：

METALLOCENE DIHALIDES; TITANOCENE DIBROMIDE; X-RAY ANALYSIS;

D O I：

10.1002/zaac.19936191117

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The crystal and molecular structure of Bis(eta5-cyclopentadienyl)titanium(IV) dibromide, Ti(eta5-C5H5)2Br2, has been investigated by an X-ray structure determination. Crystal data: triclinic, a = 7.872(5), b = 11.807(5), c = 12.310(3) angstrom, alpha = 107.62(3), beta = 100.83(4), gamma = 90.69(4)-degrees, V = 1068(14) angstrom3, T = 293, space group P1BAR, Z = 4 (there are two crystallographically independent molecules in the asymmetric unit cell and their conformations are similar). Final R and R(w) values are 0.068 and 0.073, respectively. The structural results are compared to those for similar type molecules.

引用

页码：1927 / 1930

页数：4

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