CATALYTIC-HYDROGENATION OF ESTERS OVER PD/ZNO

被引：34

作者：

WEHNER, PS

GUSTAFSON, BL

机构：

[1] Eastman Chemical Company, Catalysis Research Laboratory, Kingsport, TN 37662

来源：

JOURNAL OF CATALYSIS | 1992年 / 135卷 / 02期

关键词：

D O I：

10.1016/0021-9517(92)90043-H

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The vapor phase hydrogenation of methyl acetate has been studied using Pd/ZnO catalysts. This catalyst system is active for the conversion of methyl acetate to methanol and ethanol at pressures below 1000 psig (ca. 68 bar). The addition of small amounts of H20 to the liquid feed significantly lowers the rate of by-product formation. This catalyst has also been used for the hydrogenation of methyl propionate, methyl butyrates, and ethyl acetate. © 1992.

引用

页码：420 / 426

页数：7

共 13 条

[1]

[Anonymous], 1979, CATALYTIC HYDROGENAT

[2]

BRADLEY MW, 1983, Patent No. 74193

[3]

BRADLEY MW, 1990, Patent No. 4929777

[4]

ELMANSOUR A, 1989, ANGEW CHEM, V101, P360