2,2'-BIPYRIMIDINEOXALATOCOPPER(II) COMPLEXES - FROM THE MONONUCLEAR COMPLEX TO THE 2D SHEET-LIKE POLYMER

被引：123

作者：

DEMUNNO, G

JULVE, M

NICOLO, F

LLORET, F

FAUS, J

RUIZ, R

SINN, E

机构：

[1] UNIV VALENCIA,FAC QUIM,DEPT QUIM INORGAN,DR MOLINER 50,E-46100 BURJASSOT,SPAIN

[2] UNIV CALABRIA,DIPARTIMENTO CHIM,I-87030 ARCAVACATA,ITALY

[3] UNIV MESSINA,DIPARTIMENTO CHIM & STRUTTURA MOLEC,I-98100 MESSINA,ITALY

[4] UNIV HULL,SCH CHEM,HULL HU6 7RX,N HUMBERSIDE,ENGLAND

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1993年 / 32卷 / 04期

关键词：

D O I：

10.1002/anie.199306131

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

An unusual two‐dimensional mesh of CuII ions is found in complex 1(see picture); the metal atoms are bridged by oxalato (ox) and bipyrimidine (bpym) ligands to form ringshaped hexamers. Variable‐temperature magnetic susceptibility measurements indicate that antiferromagnetic coupling between the Cu atoms occurs. (Formula Presented.) (Figure Presented.) Copyright © 1993 by VCH Verlagsgesellschaft mbH, Germany

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页码：613 / 615

页数：3

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