COVALENT LINKAGE OF [MN4O2(O(2)CPH)(6)(DBM)(2)] INTO A DIMER AND A ONE-DIMENSIONAL POLYMER (DBMH=DIBENZOYLMETHANE)

被引：45

作者：

WANG, S

TSAI, HL

FOLTING, K

MARTIN, JD

HENDRICKSON, DN

CHRISTOU, G

机构：

[1] UNIV CALIF SAN DIEGO,DEPT CHEM 0506,LA JOLLA,CA 92093

[2] INDIANA UNIV,DEPT CHEM,BLOOMINGTON,IN 47405

[3] INDIANA UNIV,CTR MOLEC STRUCT,BLOOMINGTON,IN 47405

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1994年 / 05期

关键词：

D O I：

10.1039/c39940000671

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Methods have been developed for covalently linking [Mn4O2(O(2)CPh)(6)(dbm)(2)] 2 (dbmH = dibenzoylmethane) units to give a dimer and a polymer; treatment of 2 with trans-1,2-bis(4-pyridyl)ethene (bpe) or 4,4'-bipyridine (4,4'-bpy) yields [Mn4O2(O(2)CPh)(6)(dbm)(2)(bpe)](2) 4 and [Mn4O2(O(2)CPh)(6)(dbm)(2)(4,4'-bpy)](n) 5, respectively.

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页码：671 / 673

页数：3

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