FORMATION OF HETEROBICYCLIC COMPOUNDS THROUGH SUCCESSIVE INSERTION OF ISOCYANIDES INTO A PALLADIUM HYDRIDE BOND

被引：13

作者：

TANASE, T

OHIZUMI, T

KOBAYASHI, K

YAMAMOTO, Y

机构：

[1] TOHO UNIV,FAC SCI,DEPT CHEM,FUNABASHI,CHIBA 274,JAPAN

[2] INST PHYS & CHEM RES,WAKO,SAITAMA 351,JAPAN

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1992年 / 09期

关键词：

D O I：

10.1039/c39920000707

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Reaction of PdCl2(PPh3)2 1 with an excess of H2SiMePh and 2,6-xylyl isocyanide gives Pd{C(= NR)C(= NR)C(= NR)C(= NR)CH(= NR)}(C = NR)Cl.1/2C6H6 (3, R = 2,6-xylyl) and heterobicyclic compound, 2,6-(2',6'-xylyl)2-3,7-(N-2',6'-xylylimino)2-4,8-(N-2',6'-xylylamino)2-2,6-diaza-bicyclo[3.3.0]octa-4,8-diene 4; the structures of which have been determined by X-ray analysis.

引用

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页码：707 / 708

页数：2

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