(LIQUID+LIQUID) EQUILIBRIA OF (WATER+ETHANOL+CYCLOHEXANE) AT THE TEMPERATURES 298.15-K AND 323.15-K

被引:8
作者
MORIYOSHI, T
UOSAKI, Y
TAKAHASHI, K
YAMAKAWA, T
机构
[1] Department of Chemical Science and Technology, Faculty of Engineering, University of Tokushima, Tokushima
关键词
D O I
10.1016/S0021-9614(05)80056-4
中图分类号
O414.1 [热力学];
学科分类号
摘要
Experimental tie lines for (water + ethanol + cyclohexane) have been determined at the temperatures 298.15 K and 323.15 K. An elevation of temperature led to the results: the immiscibility region contracts slightly; the distribution curves of ethanol shift in the direction of enhancing the solubility of ethanol in the organic phase; the plait-point shifts towards the aqueous phase at higher mole fraction of ethanol; and a selectivity in extraction increases extremely in the region of lower mole fraction of ethanol in the organic phase. The present results are also compared with those for the ternary mixtures with other C6 hydrocarbons. © 1991 Academic Press Limited All rights reserved.
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页码:37 / 42
页数:6
相关论文
共 8 条
[1]  
BARTON AF, 1983, CRC HDB SOLUBILITY P, P142
[2]   (LIQUID+LIQUID) EQUILIBRIA OF (WATER PLUS ETHANOL PLUS A C8 ALKANOL) FROM 0.1 TO 200 MPA AT 298.15-K [J].
MORIYOSHI, T ;
SAKAMOTO, T ;
UOSAKI, Y .
JOURNAL OF CHEMICAL THERMODYNAMICS, 1989, 21 (09) :947-954
[3]   (LIQUID + LIQUID) EQUILIBRIA OF (WATER + ETHANOL + NORMAL-HEXANE) FROM 0.1 TO 200 MPA AT 298.15-K [J].
MORIYOSHI, T ;
UOSAKI, Y ;
MATSUURA, H ;
NISHIMOTO, W .
JOURNAL OF CHEMICAL THERMODYNAMICS, 1988, 20 (05) :551-557
[4]   (LIQUID + LIQUID) EQUILIBRIA OF (WATER + ETHANOL + TRICHLOROMETHANE) FROM 0.1 TO 200 MPA AT 298.15-K [J].
MORIYOSHI, T ;
UOSAKI, Y ;
SAKAMOTO, T .
JOURNAL OF CHEMICAL THERMODYNAMICS, 1988, 20 (05) :589-593
[5]  
Riddick JA., 1986, PHYS PROPERTIES METH
[6]  
TARASENKOV DN, 1937, ZH OBSHCH KHIM, V7, P2143
[7]   A study of solutions of ethyl alcohol in cyclohexane, in water, and in cyclohexane and water [J].
Vold, RD ;
Washburn, ER .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1932, 54 :4217-4225
[8]  
YICHUNG C, 1953, IND ENG CHEM, V45, P2350