SYNTHESIS AND PROPERTIES OF ACYCLIC AND CRYPTATE EUROPIUM(III) COMPLEXES INCORPORATING THE 3,3'-BIISOQUINOLINE 2,2'-DIOXIDE UNIT

被引：65

作者：

LEHN, JM ^{[1
]}

PIETRASZKIEWICZ, M ^{[1
]}

KARPIUK, J ^{[1
]}

机构：

[1] POLISH ACAD SCI,INST PHYS CHEM,PL-01224 WARSAW,POLAND

来源：

HELVETICA CHIMICA ACTA | 1990年 / 73卷 / 01期

关键词：

D O I：

10.1002/hlca.19900730111

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The lithium and europium(III) cryptates of a macrobicyclic ligand 1 incorporating the 3,3′‐biisoquinoline 2,2′‐dioxide 2 have been prepared. The Eu(III) complex [Eu(2)2]Cl3 has also been obtained. These Eu(III) complexes present characteristic 1H‐NMR spectra containing markedly shifted resonances. They are strongly luminescent; the emission spectra, quantum yields, and lifetimes have been determined. Copyright © 1990 Verlag GmbH & Co. KGaA, Weinheim

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页码：106 / 111

页数：6

相关论文

共 27 条

[1] CRYSTAL-STRUCTURE OF TETRAKIS(2,2'-BIPYRIDINE DIOXIDE)LANTHANUM PERCHLORATE - EXAMPLE OF CUBIC EIGHT-COORDINATION [J].

ALKARAGHOULI, AR ;

DAY, RO ;

WOOD, JS .

INORGANIC CHEMISTRY, 1978, 17 (12) :3702-3706

[2] SYNTHESIS AND CHARACTERIZATION OF THE SODIUM AND LITHIUM CRYPTATES OF MACROBICYCLIC LIGANDS INCORPORATING PYRIDINE, BIPYRIDINE, AND BIISOQUINOLINE UNITS [J].

ALPHA, B ;

ANKLAM, E ;

DESCHENAUX, R ;

LEHN, JM ;

PIETRASKIEWICZ, M .

HELVETICA CHIMICA ACTA, 1988, 71 (05) :1042-1052

[3]

Alpha B., 1987, ANGEW CHEM, V99, P259, DOI DOI 10.1002/ANGE.19870990323

[4]

Alpha B., 1987, ANGEW CHEM, V99, P1310, DOI DOI 10.1002/ANGE.19870991226

[5]

ALPHA B, 1987, THESIS U L PASTEUR S

[6] CAGED AND UNCAGED RUTHENIUM(II) POLYPYRIDINE COMPLEXES - COMPARATIVE-STUDY OF THE PHOTOCHEMICAL, PHOTOPHYSICAL, AND ELECTROCHEMICAL PROPERTIES [J].

BARIGELLETTI, F ;

DECOLA, L ;

BALZANI, V ;

BELSER, P ;

VONZELEWSKY, A ;

VOGTLE, F ;

EBMEYER, F ;

GRAMMENUDI, S .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1989, 111 (13) :4662-4668

[7] PHOTOACTIVE CRYPTANDS - CRYSTAL-STRUCTURE OF THE SODIUM CRYPTATE OF THE TRIS(PHENANTHROLINE) MACROBICYCLIC LIGAND [J].

CARON, A ;

GUILHELM, J ;

RICHE, C ;

PASCARD, C ;

ALPHA, B ;

LEHN, JM ;

RODRIGUEZUBIS, JC .

HELVETICA CHIMICA ACTA, 1985, 68 (06) :1577-1582

[8] CRYPTATES .10. SYNTHESIS AND PHYSICAL PROPERTIES OF DIAZAPOLYOXAMACROBICYCLIC SYSTEMS [J].

DIETRICH, B ;

LEHN, JM ;

SAUVAGE, JP ;

BLANZAT, J .

TETRAHEDRON, 1973, 29 (11) :1629-1645

[9]

DURR H, 1988, Z NATURFORSCH B, V43, P361

[10]

GUILHEM J, UNPUB