CYCLOADDITIONS .48. ADDITION OF PHOTOCHEMICALLY GENERATED ACYLNITRENES TO C-60 - SYNTHESIS OF FULLEROAZIRIDINES AND THERMAL REARRANGEMENT TO FULLEROOXAZOLES

被引：48

作者：

AVERDUNG, J

MATTAY, J

JACOBI, D

ABRAHAM, W

机构：

[1] UNIV MUNSTER,INST ORGAN CHEM,D-48149 MUNSTER,GERMANY

[2] HUMBOLDT UNIV BERLIN,INST CHEM,D-10115 BERLIN,GERMANY

来源：

TETRAHEDRON | 1995年 / 51卷 / 09期

关键词：

60]FULLERENE; AZIRIDINE; OXAZOLE; NITRENE; AZIDE; PHOTOREACTION;

D O I：

10.1016/0040-4020(95)00013-X

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The reaction of C-60 to acylnitrenes 2, generated by photolysis of aroylazides 1 in dichloromethane, creates the stable fulleroaziridine derivatives 3a, 3b, 3c, and 3d. The rearrangement of the fulleroaziridines 3 by boiling in tetrachloroethane leads to the formation of the corresponding fullerooxazoles 4a, 4b, 4c, and 4d. The formation of a fullerooxazole 4b was also observed by irradiation of C-60 and 1b in benzene.

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页码：2543 / 2552

页数：10

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