N-(8-QUINOLYL)-N'-(2-PYRIDYLMETHYL)MALONAMIDE DERIVATIVES AS A NOVEL CU(II) CARRIER WITH HIGH-EFFICIENCY AND SELECTIVITY FOR PROTON-DRIVEN UPHILL TRANSPORT THROUGH LIQUID MEMBRANES

被引：19

作者：

HIRATANI, K ^{[1
]}

HIROSE, T ^{[1
]}

KASUGA, K ^{[1
]}

SAITO, K ^{[1
]}

机构：

[1] TOIN UNIV YOKOHAMA,DEPT MAT SCI & TECHNOL,MIDORI KU,YOKOHAMA,KANAGAWA 227,JAPAN

来源：

JOURNAL OF ORGANIC CHEMISTRY | 1992年 / 57卷 / 26期

关键词：

D O I：

10.1021/jo00052a019

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Several N,N'-disubstituted malonamide derivatives have been designed as a carrier for ion transport. Their ability to transport transition-metal ions through liquid membranes has been investigated. It has been found that N-(8-quinolyl)-N'-(2-pyridylmethyl)malonamide derivatives can transport Cu(II) with high efficiency and selectivity against its concentration gradient from nearly a neutral aqueous phase (pH 6.2) to an acidic aqueous phase through a chloroform liquid membrane.

引用

页码：7083 / 7087

页数：5

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