THE NEUTRALIZATION OF HEC60(.+) IN THE GAS-PHASE - COMPELLING EVIDENCE FOR THE EXISTENCE OF AN ENDOHEDRAL STRUCTURE FOR HE[C-60

被引：86

作者：

WEISKE, T

WONG, T

KRATSCHMER, W

TERLOUW, JK

SCHWARZ, H

机构：

[1] TECH UNIV BERLIN, INST ORGAN CHEM, STR 17, JUNI 135, W-1000 BERLIN 12, GERMANY

[2] MCMASTER UNIV, DEPT CHEM, HAMILTON L8S 4M1, ONTARIO, CANADA

[3] MAX PLANCK INST NUCL PHYS, W-6900 HEIDELBERG 1, GERMANY

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 1992年 / 31卷 / 02期

关键词：

D O I：

10.1002/anie.199201831

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Neutralization‐reionization mass spectrometry was used to show that for both neutral He@C60 and He@C 60˙+, the noble gas atom is incorporated within the fullerene cavity. The C60H˙+ ions were generated by high‐energy collisions of C 60˙+ with quasi‐stationary 4He target atoms and cleaved in the mass spectrometer by loss of C2 or multiples thereof, as is usual for endohedral MC60 complexes. Copyright © 1992 by VCH Verlagsgesellschaft mbH, Germany

引用

页码：183 / 185

页数：3

共 59 条

[1] MNDO STUDY OF LARGE CARBON CLUSTERS [J].