SYNTHESIS OF A NEW CHITIN DERIVATIVE, (1-CARBOXYETHYL)CHITOSAN

被引：24

作者：

SHIGEMASA, Y ^{[1
]}

ISHIDA, A ^{[1
]}

SASHIWA, H ^{[1
]}

SAIMOTO, H ^{[1
]}

OKAMOTO, Y ^{[1
]}

MINAMI, S ^{[1
]}

MATSUHASHI, A ^{[1
]}

机构：

[1] TOTTORI UNIV,FAC AGR,DEPT VET SURG,TOTTORI 680,JAPAN

来源：

CHEMISTRY LETTERS | 1995年 / 08期

关键词：

D O I：

10.1246/cl.1995.623

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A new chitin derivative, (1-carboxyethyl)chitosan, was synthesized from chitin and chitosan by the reaction with 2-chloropropionic acid, and its activation effect on canine polymorphonuclear cells (PMNs) was evaluated. The degree of substitution was increased by the repetition of the reaction, but the simultaneous N-deacetylation proceeded. N-Selective 1-carboxyethylation of chitosan was achieved by reductive N-alkylation with 2-oxopropionic acid and NaBH4.

引用

页码：623 / 624

页数：2

共 50 条

[21] Synthesis of acylated chitin and chitosan derivatives [J].

Vasnev, VA ;

Tarasov, AI ;

Pripadchev, DA ;

Menyailo, YA ;

Garkusha, OG .

POLYMER SCIENCE SERIES A, 2003, 45 (09) :833-839

[22] Synthesis and NMR studies of methyl 3-O-[(R)- and (S)-1-carboxyethyl]-α-D-gluco-, galacto- and mannopyranosides [J].

Andersson, L ;

Kenne, L .

CARBOHYDRATE RESEARCH, 1998, 313 (3-4) :157-164

[23] SYNTHESIS AND CHROMATOGRAPHIC PROPERTIES OF S-(1-CARBOXYETHYL)-L-CYSTEINE AND S-(1-CARBOXYPROPYL)-L-CYSTEINE [J].

BLARZINO, C ;

FOPPOLI, C ;

COCCIA, R .

ITALIAN JOURNAL OF BIOCHEMISTRY, 1987, 36 (01) :1-7

[24] A NOVEL-APPROACH FOR STEREOCHEMICAL ANALYSIS OF 1-CARBOXYETHYL SUGAR ETHERS BY NMR-SPECTROSCOPY [J].

SEVERN, WB ;

RICHARDS, JC .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1993, 115 (03) :1114-1120

[25] The new technologies in chitin/chitosan preparation [J].

Yang, Shoufeng ;

Zhang, Hongcai ;

Shi, Yixiang ;

Wan, Ajun .

ENVIRONMENT-ENHANCING ENERGY AND BIOCHEMICALS CONFERENCE II, 2013, 666 :143-150

[26] Synthesis and adsorption properties of N,O-carboxyethyl-chitosan [J].

Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou 730000, China ;

不详 .

Gaofenzi Cailiao Kexue Yu Gongcheng, 2006, 3 (25-29)

[27] Synthesis of a new chitosan derivative and assay of Escherichia coli adsorption [J].

BingBing ShangJun ShaYang LiuQin TuManLin LiJinYi Wang College of ScienceNorthwest Agricultural Forestry UniversityYanglingShaanxi China Shaanxi Key Laboratory of Molecular Biology for AgricultureNorthwest Agricultural Forestry UniversityYanglingShaanxi China .

Journal of Pharmaceutical Analysis, 2011, 1 (01) :39-45

[28] Synthesis of a new chitosan derivative and assay of Escherichia coli adsorption [J].

Shang, Bing-Bing ;

Sha, Jun ;

Liu, Yang ;

Tu, Qin ;

Li, Man-Lin ;

Wang, Jin-Yi .

JOURNAL OF PHARMACEUTICAL ANALYSIS, 2011, 1 (01) :39-45

[29] Thiolated chitosan-lauric acid as a new chitosan derivative: Synthesis, characterization and cytotoxicity [J].

Kazemi, Mir Salar ;

Mohammadi, Zohreh ;

Amini, Mohsen ;

Yousefi, Maryam ;

Tarighi, Parastoo ;

Eftekhari, Samane ;

Tehrani, Morteza Rafiee .

INTERNATIONAL JOURNAL OF BIOLOGICAL MACROMOLECULES, 2019, 136 :823-830

[30] Chitin, Chitosan, and Nanochitin: Extraction, Synthesis, and Applications [J].

Kozma, Michael ;

Acharya, Bishnu ;

Bissessur, Rabin .

POLYMERS, 2022, 14 (19)

← 1 2 3 4 5 →