REACTIONS OF (1-CHLOROVINYL)DIPHENYLPHOSPHINE OXIDE WITH ORGANOMETALLIC REAGENTS

被引：12

作者：

CARDELLICCHIO, C

FIANDANESE, V

NASO, F

PIETRUSIEWICZ, KM

WISNIEWSKI, W

机构：

[1] CNR,DIPARTIMENTO CHIM,CTR STUDIO METODOL INNOVAT SINTESI ORGANICHE,I-70126 BARI,ITALY

[2] POLISH ACAD SCI,CTR MOLEC & MACROMOLEC STUDIES,PL-90363 LODZ,POLAND

来源：

TETRAHEDRON LETTERS | 1993年 / 34卷 / 19期

关键词：

D O I：

10.1016/S0040-4039(00)93399-9

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Direct substitution of 1-chlorovinyl group by an aryl or an alkyl group in the reactions of (1-chlorovinyl)diphenylphosphine oxide with aryl and alkyl Grignard reagents was observed, whereas in its reactions with the corresponding cuprates addition across the double bond constituted the dominant reaction pathway.

引用

收藏

页码：3135 / 3138

页数：4

相关论文

共 20 条

[11] DIRECT CONFIGURATIONAL CORRELATION OF TRIALKYL- AND TRIARYLPHOSPHINE OXIDES [J].

LEWIS, RA ;

MISLOW, K .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1969, 91 (25) :7009-&

[12] REACTIONS BETWEEN LITHIUM DIMETHYLCUPRATE AND ALKENYL BROMIDES, CHLORIDES, AND FLUORIDES - SYNTHETIC, MECHANISTIC, AND STEREOCHEMICAL ASPECTS [J].

MAFFEO, CV ;

MARCHESE, G ;

NASO, F ;

RONZINI, L .

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1, 1979, (01) :92-97

[13]

MAIER L, 1961, CHEM BER-RECL, V94, P3043

[14] THE ACTION OF GRIGNARD REAGENTS ON DIARYL PHOSPHINYL CHLORIDES [J].

MORRISON, DC .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1950, 72 (10) :4820-4820

[15] RETENTION OF CONFIGURATION IN LIGAND COUPLING REACTIONS IN SIGMA-SULFURANES [J].

OAE, S ;

TAKEDA, T ;

WAKABAYASHI, S ;

IWASAKI, F ;

YAMAZAKI, N ;

KATSUBE, Y .

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2, 1990, (02) :273-276

[16] LIGAND COUPLING WITHIN SIGMA-SULFURANE INTERMEDIATES FORMED IN THE REACTION OF BENZYL 2-PYRIDYL AND RELATED SULFOXIDES WITH GRIGNARD-REAGENTS [J].

OAE, S ;

KAWAI, T ;

FURUKAWA, N ;

IWASAKI, F .

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2, 1987, (03) :405-411

[17]

PIETRUSIEWICZ KM, 1989, TETRAHEDRON, V45, P337

[18]

Rappoport Z., 1969, ADV PHYS ORG CHEM, V7, P1

[19]

ROZEN AM, 1983, RADIOKHIMIYA, V25, P609

[20] LIGAND COUPLING REACTION ON THE PHOSPHORUS ATOM [J].

UCHIDA, Y ;

ONOUE, K ;

TADA, N ;

NAGAO, F .

TETRAHEDRON LETTERS, 1989, 30 (05) :567-570