SYNTHESIS AND CHARACTERIZATION OF GLYCIDYL METHACRYLATE STYRENE COPOLYMERS AND DETERMINATION OF MONOMER REACTIVITY RATIOS

被引：30
|
作者：
SOUNDARARAJAN, S [1 ]
REDDY, BSR [1 ]
RAJADURAI, S [1 ]
机构：
[1] CENT LEATHER RES INST,MADRAS 600020,TAMIL NADU,INDIA
来源：
POLYMER | 1990年 / 31卷 / 02期
关键词：
characterization; copolymerization; glycidyl methacrylate; reactivity ratios; styrene;
D O I：
10.1016/0032-3861(90)90135-L
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
Copolymers of glycidyl methacrylate (GMA) and styrene were prepared in the presence of 2,2'-azobisisobutyronitrile in chlorobenzene. The polymers were characterized by infra-red and 13C nuclear magnetic resonance spectroscopy. The percentage of GMA present in the copolymers was established by elemental analysis. The copolymerization reactivity ratios were calculated using the Kelen-Tudos method. Molecular weights, glass transition temperatures and thermal properties were determined by gel permeation chromatography, differential scanning calorimetry and thermogravimetric analysis, respectively. © 1990.
引用
收藏
页码：366 / 370
页数：5
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