LONG-RANGE COUPLING IN CYCLOHEXANE FRAGMENTS

被引：12
作者：
CAREY, PR
DITCHFIELD, R
机构：
[1] The Chemical Laboratory, University of Sussex, Brighton, BN1 9QJ, Falmer
来源：
MOLECULAR PHYSICS | 1968年 / 15卷 / 05期
关键词：
D O I：
10.1080/00268976800101411
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Couplings over four bonds, 4JHH, are discussed for compounds where stereochemistry is thought to be the dominant factor determining their values. A simple MO theory [3, 4] provides calculated coupling constants in agreement with experiment. The form of the theory permits an analysis of the mechanisms responsible for long-range coupling. The approach is generalized to include distorted cyclohexane fragments and these results are presented in a graphical form. © 1968 Taylor and Francis Group, LLC.
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页码：515 / +
页数：1
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