THE OXENOID CHARACTER OF METALATED HYDROPEROXIDES O(M)OR - OXIDATION OF ORGANOMETALLIC COMPOUNDS R'M' TO R'OH UNDER MILD CONDITIONS

被引：29
作者：
BOCHE, G
BOSOLD, F
LOHRENZ, JCW
机构：
[1] Fachbereich Chemie, Universität Marburg
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 1994年 / 33卷 / 11期
关键词：
D O I：
10.1002/anie.199411611
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The oxygen analogues of carbenoids 1 and nitrenoids 2, namely the lithiated hydroperoxides 3, are more electrophilic than the corresponding nonlithiated derivatives. These “oxenoids” can convert organometallic compounds R′M′, including cuprates, into alcohols under mild conditions. (Figure Presented.) Copyright © 1994 by VCH Verlagsgesellschaft mbH, Germany
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页码：1161 / 1163
页数：3
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