A USEFUL SYNTHESIS OF CHIRAL SULFONYL CYANIDES - (1S,2S,5R)-2-ISOPROPYL-5-METHYLCYCLOHEXANESULFONYL CYANIDE

被引：25

作者：

BLANCO, JM ^{[1
]}

CAAMANO, O ^{[1
]}

FERNANDEZ, F ^{[1
]}

GOMEZ, G ^{[1
]}

LOPEZ, C ^{[1
]}

机构：

[1] UNIV SANTIAGO,FAC FARM,DEPT QUIM ORGAN,E-15706 SANTIAGO,SPAIN

来源：

TETRAHEDRON-ASYMMETRY | 1992年 / 3卷 / 06期

关键词：

D O I：

10.1016/S0957-4166(00)80515-7

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A convenient method for the preparation of chiral alkanesulfonyl cyanides, by oxidation of readily available alkyl thiocyanates with m-ClC6H4CO3H, has been developed.

引用

页码：749 / 752

页数：4

共 14 条

[1]

BLANCO JM, 1990, SYNTHESIS-STUTTGART, P584

[2] SYNTHESIS OF SULFINYL CYANIDES [J].

BOERMAMARKERINK, A ;

JAGT, JC ;

MEYER, H ;

WILDEMAN, J ;

VANLEUSEN, AM .

SYNTHETIC COMMUNICATIONS, 1975, 5 (02) :147-154

[3]

CAAMANO O, 1988, HETEROCYCLES, V27, P2839

[4] SYNTHESIS OF CARBOCYCLIC AMINONUCLEOSIDES [J].

DALUGE, S ;

VINCE, R .

JOURNAL OF ORGANIC CHEMISTRY, 1978, 43 (12) :2311-2320

[5] DIELS-ALDER CYCLOADDITIONS OF SULFONYL CYANIDES WITH CYCLOPENTADIENE - SYNTHESIS OF "2-AZABICYCLO[2.2.1]HEPTA-2,5-DIENES [J].

JAGT, JC ;

VANLEUSE.AM .

JOURNAL OF ORGANIC CHEMISTRY, 1974, 39 (04) :564-566

[6]

JAGT JC, 1973, RECL TRAV CHIM PAY B, V92, P1343

[7]

JAGT JC, 1975, RECL TRAV CHIM PAY B, V94, P12

[8] KINETIC CYANATIONS OF KETONE ENOLATES [J].

KAHNE, D ;

COLLUM, DB .

TETRAHEDRON LETTERS, 1981, 22 (50) :5011-5014

[9]

MIKOLAJCZYK M, 1987, SYNTHESIS-STUTTGART, P1009

[10]

PEWS RG, 1969, J CHEM SOC CHEM COMM, P1187

← 1 2 →