CLUSTER CHEMISTRY .70. PREPARATION AND X-RAY STRUCTURE OF RU3(MU-3-C2(CO2ME)2)(MU-CO)(CO)7(PME2PH)2

被引：16

作者：

BRUCE, MI ^{[1
]}

HUMPHREY, PA ^{[1
]}

MIYAMAE, H ^{[1
]}

WHITE, AH ^{[1
]}

机构：

[1] UNIV WESTERN AUSTRALIA,SCH CHEM,NEDLANDS,WA 6009,AUSTRALIA

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1991年 / 417卷 / 03期

基金：

澳大利亚研究理事会;

关键词：

D O I：

10.1016/0022-328X(91)80202-U

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The title complex has been obtained from a reaction between Ru3(CO)10(PMe2Ph)2 and C2(CO2Me)2. The alkyne is attached to the closed triangular Ru3 cluster in the usual mu-3-eta-2-parallel-to mode, the two Ru atoms to which the alkyne is sigma-bonded also bearing the PMe2Ph ligands, and being bridged by a CO group. A minor product also isolated from this reaction was partially characterised as Ru3{C2(CO2Me)2}3(CO)6-(PMe2Ph)2.

引用

页码：431 / 437

页数：7

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