CH3F SPIN-MODIFICATION CONVERSION INDUCED BY NUCLEAR MAGNETIC DIPOLE-DIPOLE INTERACTIONS

被引:66
作者
CHAPOVSKY, PL
机构
[1] Institute of Automation and Electrometry
来源
PHYSICAL REVIEW A | 1991年 / 43卷 / 07期
关键词
D O I
10.1103/PhysRevA.43.3624
中图分类号
O43 [光学];
学科分类号
070207 ; 0803 ;
摘要
A theory has been constructed for the CH3F molecule's nuclear-spin conversion induced by the intramolecular magnetic dipole-dipole nuclei interaction. It is shown that for 13CH3F molecules this mechanism leads to the rate of spin conversion (0.71 +/- 0.2)X10(-2) s-1/Torr, which is approximately one-half of the experimentally registered value.
引用
收藏
页码:3624 / 3630
页数:7
相关论文
共 11 条
[1]  
Bunker P. R., 2006, MOL SYMMETRY SPECTRO
[2]  
CHAPOVSKY PL, 1990, ZH EKSP TEOR FIZ, V70, P895
[3]   NUCLEAR SPIN STATE EQUILIBRATION THROUGH NONMAGNETIC COLLISIONS [J].
CURL, RF ;
KASPER, JVV ;
PITZER, KS .
JOURNAL OF CHEMICAL PHYSICS, 1967, 46 (08) :3220-&
[4]   AVERAGE AND EQUILIBRIUM STRUCTURES OF METHYL-FLUORIDE STUDIED BY ELECTRON-DIFFRACTION - A JOINT ANALYSIS WITH ROTATIONAL-CONSTANTS AND CUBIC FORCE-CONSTANTS [J].
EGAWA, T ;
YAMAMOTO, S ;
NAKATA, M ;
KUCHITSU, K .
JOURNAL OF MOLECULAR STRUCTURE, 1987, 156 (3-4) :213-228
[5]  
EGAWA T, COMMUNICATION
[6]   DETERMINATION OF A0 FOR CH3F FROM GROUND-STATE COMBINATION DIFFERENCES [J].
GRANER, G .
MOLECULAR PHYSICS, 1976, 31 (06) :1833-1843
[7]   TIME-RESOLVED INFRARED-MICROWAVE DOUBLE-RESONANCE IN CH-133F - THEORY AND EXPERIMENT [J].
JETTER, H ;
PEARSON, EF ;
NORRIS, CL ;
MCGURK, JC ;
FLYGARE, WH .
JOURNAL OF CHEMICAL PHYSICS, 1973, 59 (04) :1796-1804
[8]  
Landau L. D., 1974, QUANTUM MECH NONRELA
[9]   INFRARED MICROWAVE SIDE-BAND LASER SPECTROSCOPY OF THE NV-3 AND 2-NV-3 [- NU-3 BANDS OF (CH3F)-C-13 [J].
LEE, SK ;
SCHWENDEMAN, RH ;
MAGERL, G .
JOURNAL OF MOLECULAR SPECTROSCOPY, 1986, 117 (02) :416-434
[10]   STUDY OF THE NU-3 AND 2NU3 [- NU-3 BANDS OF (CH3F)-C-12 BY INFRARED-LASER SIDE-BAND AND SUBMILLIMETER-WAVE SPECTROSCOPY [J].
LEE, SK ;
SCHWENDEMAN, RH ;
CROWNOVER, RL ;
SKATRUD, DD ;
DELUCIA, FC .
JOURNAL OF MOLECULAR SPECTROSCOPY, 1987, 123 (01) :145-160