Optimization of shrimp shell waste deacetylation for chitosan production

被引:12
作者
Ahing, Flornica Alca [1 ]
Wid, Newati [1 ]
机构
[1] Univ Malaysia Sabah, Fac Sci & Nat Resources, Jalan UMS, Kota Kinabalu 88400, Sabah, Malaysia
来源
INTERNATIONAL JOURNAL OF ADVANCED AND APPLIED SCIENCES | 2016年 / 3卷 / 10期
关键词
Chitosan; Shrimp shell waste; Repeat deacetylation; Chitosan solubility; Degree of deacetylation;
D O I
10.21833/ijaas.2016.10.006
中图分类号
O [数理科学和化学]; P [天文学、地球科学]; Q [生物科学]; N [自然科学总论];
学科分类号
07 ; 0710 ; 09 ;
摘要
Chitosan, a versatile natural polymer is an amino polysaccharide prepared by processing shrimp shell waste which involved deacetylation of chitin. To obtain high degree of deacetylation (DDA), several parameters should be performed during alkaline treatment. The present study was undertaken at different time of soaking treatment (once and twice) and temperature (60 degrees C and 80 degrees C) to optimize the deacetylation process to produce chitosan with high solubility and degree of deacetylation. It was observed that the highest solubility and degree of deacetylation were obtained when deacetylation process was repeated twice and temperature of 80 degrees C, with 99.48% and 97.63%, respectively. It can be concluded that by repeating the deacetylation twice with the support of heating treatment, a better quality of chitosan with higher solubility and degree of deacetylation can be produced. (C) 2016 The Authors. Published by IASE.
引用
收藏
页码:31 / 36
页数:6
相关论文
共 19 条
[1]   Extraction and characterization of chitin and chitosan from local sources [J].
Abdou, Entsar S. ;
Nagy, Khaled S. A. ;
Elsabee, Maher Z. .
BIORESOURCE TECHNOLOGY, 2008, 99 (05) :1359-1367
[2]   Extraction and characterization of chitin and chitosan from marine sources in Arabian Gulf [J].
Al Sagheer, F. A. ;
Al-Sughayer, M. A. ;
Muslim, S. ;
Elsabee, M. Z. .
CARBOHYDRATE POLYMERS, 2009, 77 (02) :410-419
[3]   Enhancement and Characterization of Chitosan Extraction from the Wastes of Shrimp Packaging Plants [J].
Alishahi, A. ;
Mirvaghefi, A. ;
Tehrani, M. R. ;
Farahmand, H. ;
Shojaosadati, S. A. ;
Dorkoosh, F. A. ;
Elsabee, Maher Z. .
JOURNAL OF POLYMERS AND THE ENVIRONMENT, 2011, 19 (03) :776-783
[4]   An infrared investigation in relation with chitin and chitosan characterization [J].
Brugnerotto, J ;
Lizardi, J ;
Goycoolea, FM ;
Argüelles-Monal, W ;
Desbrières, J ;
Rinaudo, M .
POLYMER, 2001, 42 (08) :3569-3580
[5]  
Coates J., 2000, ENCY ANAL CHEM, P10837, DOI DOI 10.1002/9780470027318.A5606
[6]  
El-hefian EA, 2009, MAEJO INT J SCI TECH, V3, P415
[7]  
Hossain M., 2014, J BANGLADESH AGRIC U, V12, P153, DOI 10.3329/jbau.v12i1.21405
[8]   A review of several reported procedures to determine the degree of N-acetylation for chitin and chitosan using infrared spectroscopy [J].
Kasaal, Mohammad R. .
CARBOHYDRATE POLYMERS, 2008, 71 (04) :497-508
[9]  
Kumari S., 2014, PROCEDIA MAT SCI, V6, P482, DOI [10.1016/j.mspro.2014.07.062, DOI 10.1016/J.MSPRO.2014.07.062]
[10]   N-ACETYLATION OF CHITOSAN FILMS [J].
MIYA, M ;
IWAMOTO, R ;
OHTA, K ;
MIMA, S .
KOBUNSHI RONBUNSHU, 1985, 42 (03) :181-189