MOLECULAR CONFIGURATION AND INTERACTIONS OF AMIDE GROUP .I. SOLVENT EFFECTS ON VIBRATIONAL FREQUENCIES

被引：59
作者：
CUTMORE, EA
HALLAM, HE
机构：
[1] Department of Chemistry, University College of Swansea, Singleton Park
来源：
SPECTROCHIMICA ACTA PART A-MOLECULAR SPECTROSCOPY | 1969年 / A 25卷 / 11期
关键词：
D O I：
10.1016/0584-8539(69)80205-9
中图分类号：
O433 [光谱学];
学科分类号：
0703 ; 070302 ;
摘要：
The vibrational frequencies of a series of primary, secondary and tertiary amides and urethanes have been studied between 4000 and 650 cm-1 in a comprehensive range of solvents. The results are discussed in terms of the electronic effects in the -CO·NH-and -O·CO·NH- groups. Estimates are given for the pKa values of primary and secondary compounds. © 1969.
引用
收藏
页码：1767 / &
相关论文
共 11 条
[1]   INFRA-RED SPECTRA AND SOLVENT EFFECTS .2. CARBONYL ABSORPTIONS [J].
BELLAMY, LJ ;
WILLIAMS, RL .
TRANSACTIONS OF THE FARADAY SOCIETY, 1959, 55 (01) :14-18
[2]   INFRA-RED SPECTRA AND SOLVENT EFFECTS .1. X-H STRETCHING FREQUENCIES [J].
BELLAMY, LJ ;
HALLAM, HE ;
WILLIAMS, RL .
TRANSACTIONS OF THE FARADAY SOCIETY, 1958, 54 (08) :1120-1127
[3]   MICROWAVE SPECTRUM AND MOLECULAR STRUCTURE OF FORMAMIDE [J].
COSTAIN, CC ;
DOWLING, JM .
JOURNAL OF CHEMICAL PHYSICS, 1960, 32 (01) :158-165
[4]  
COULSON CA, 1965, VALENCY, P361
[5]   INFRA-RED SOLVENT SHIFTS AND MOLECULAR INTERACTIONS .1. RELATIVE STRENGTHS OF PRIMARY AND SECONDARY NITROGENOUS BASES [J].
CUTMORE, EA ;
HALLAM, HE .
TRANSACTIONS OF THE FARADAY SOCIETY, 1962, 58 (469) :40-&
[6]   SOLVENT EFFECTS ON THE INFRA-RED SPECTRA OF 2-NITROANILINES [J].
DYALL, LK .
SPECTROCHIMICA ACTA, 1961, 17 (03) :291-299
[7]   SOLVENT EFFECTS ON INFRA-RED SPECTRA OF ANILINES .3. ACETANILIDES [J].
DYALL, LK ;
KEMP, JE .
SPECTROCHIMICA ACTA, 1966, 22 (03) :483-&
[8]   SOLVENT EFFECTS ON INFRA-RED SPECTRA OF ANILINES .2. N-METHYL- AND N-PHENYLANILINES [J].
DYALL, LK ;
KEMP, JE .
SPECTROCHIMICA ACTA, 1966, 22 (03) :467-&
[9]  
HALLAM HE, 1963, INFRARED SPECTROSCOP, pCH12
[10]  
JEWELL DJ, 1958, SPECTROCHIM ACTA, V13, P254
12