HIGHLY ORDERED FILMS OF NEAT CALIX[4]ARENES FOR 2ND-ORDER NONLINEAR OPTICS

被引：41
作者：
KELDERMAN, E
HEESINK, GJT
DERHAEG, L
VERBIEST, T
KLAASE, PTA
VERBOOM, W
ENGBERSEN, JFJ
VANHULST, NF
CLAYS, K
PERSOONS, A
REINHOUDT, DN
机构：
[1] UNIV TWENTE,DEPT APPL PHYS,OPTOELECTR LAB,7500 AE ENSCHEDE,NETHERLANDS
[2] UNIV LEUVEN,DEPT CHEM,B-3001 LOUVAIN,BELGIUM
[3] TNO,PLAST & RUBBER RES INST,2600 JA DELFT,NETHERLANDS
来源：
ADVANCED MATERIALS | 1993年 / 5卷 / 12期
关键词：
D O I：
10.1002/adma.19930051211
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
In substituted calix[4]-arenes-cyclophanes consisting of four phenol moieties connected by methylene bridges-the number and also the relative positions of the donor and/or acceptor pi-conjugated (D-pi-A) units can be varied by changing the configuration. The Figure illustrates the cone configuration. The molecular and thin-film NLO properties of three tetra-D-pi-A-substituted calix[4]arenes, including their orientation in thin films and the stability of their NLO properties, are described.
引用
收藏
页码：925 / 930
页数：6
相关论文
共 31 条
[21]  
Kelderman E., 1993, SUPRAMOL CHEM, P183
[22]   UNIPOLAR CORONA SPACE-CHARGE IN WIRE-PLANE GEOMETRY - A 1ST PRINCIPLES NUMERICAL COMPUTATION [J].
LI, JR ;
WINTLE, HJ .
JOURNAL OF APPLIED PHYSICS, 1989, 65 (12) :4617-4624
[23]  
LIN D, 1989, SYNTHETIC MET, V28, pD585
[24]   2ND-HARMONIC GENERATION AND ABSORPTION STUDIES OF POLYMER DYE FILMS ORIENTED BY CORONA-ONSET POLING AT ELEVATED-TEMPERATURES [J].
MORTAZAVI, MA ;
KNOESEN, A ;
KOWEL, ST ;
HIGGINS, BG ;
DIENES, A .
JOURNAL OF THE OPTICAL SOCIETY OF AMERICA B-OPTICAL PHYSICS, 1989, 6 (04) :733-741
[25]  
STARING EGJ, 1991, RECL TRAV CHIM PAY B, V110, P492
[26]   ORGANIC MATERIALS FOR FREQUENCY DOUBLING [J].
STARING, EGJ ;
RIKKEN, GLJA ;
SEPPEN, CJE ;
NIJHUIS, S ;
VENHUIZEN, AHJ .
ADVANCED MATERIALS, 1991, 3 (7-8) :401-403
[27]   SIMPLE REFLECTION TECHNIQUE FOR MEASURING THE ELECTROOPTIC COEFFICIENT OF POLED POLYMERS [J].
TENG, CC ;
MAN, HT .
APPLIED PHYSICS LETTERS, 1990, 56 (18) :1734-1736
[28]   ELECTRIC-FIELD POLING OF ACCEPTOR DONOR MOLECULES [J].
VANDERVORST, CPJM ;
PICKEN, SJ .
JOURNAL OF THE OPTICAL SOCIETY OF AMERICA B-OPTICAL PHYSICS, 1990, 7 (03) :320-325
[29]   SELECTIVE FUNCTIONALIZATION OF CALIX[4]ARENES AT THE UPPER RIM [J].
VANLOON, JD ;
ARDUINI, A ;
COPPI, L ;
VERBOOM, W ;
POCHINI, A ;
UNGARO, R ;
HARKEMA, S ;
REINHOUDT, DN .
JOURNAL OF ORGANIC CHEMISTRY, 1990, 55 (21) :5639-5646
[30]  
WILLIAMS DJ, 1984, ANGEW CHEM, V96, P637
1234