HIGHLY ORDERED FILMS OF NEAT CALIX[4]ARENES FOR 2ND-ORDER NONLINEAR OPTICS

被引：41
作者：
KELDERMAN, E
HEESINK, GJT
DERHAEG, L
VERBIEST, T
KLAASE, PTA
VERBOOM, W
ENGBERSEN, JFJ
VANHULST, NF
CLAYS, K
PERSOONS, A
REINHOUDT, DN
机构：
[1] UNIV TWENTE,DEPT APPL PHYS,OPTOELECTR LAB,7500 AE ENSCHEDE,NETHERLANDS
[2] UNIV LEUVEN,DEPT CHEM,B-3001 LOUVAIN,BELGIUM
[3] TNO,PLAST & RUBBER RES INST,2600 JA DELFT,NETHERLANDS
来源：
ADVANCED MATERIALS | 1993年 / 5卷 / 12期
关键词：
D O I：
10.1002/adma.19930051211
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
In substituted calix[4]-arenes-cyclophanes consisting of four phenol moieties connected by methylene bridges-the number and also the relative positions of the donor and/or acceptor pi-conjugated (D-pi-A) units can be varied by changing the configuration. The Figure illustrates the cone configuration. The molecular and thin-film NLO properties of three tetra-D-pi-A-substituted calix[4]arenes, including their orientation in thin films and the stability of their NLO properties, are described.
引用
收藏
页码：925 / 930
页数：6
相关论文
共 31 条
[1]   POLYMERS FOR NONLINEAR OPTICS [J].
BUCKLEY, A .
ADVANCED MATERIALS, 1992, 4 (03) :153-158
[2]  
Chemla D. S., 1987, NONLINEAR OPTICAL PR, V1
[3]  
Chemla D.S., 1987, NONLINEAR OPTICAL PR, V2
[4]   EXPERIMENTAL INVESTIGATIONS OF ORGANIC MOLECULAR NONLINEAR OPTICAL POLARIZABILITIES .1. METHODS AND RESULTS ON BENZENE AND STILBENE DERIVATIVES [J].
CHENG, LT ;
TAM, W ;
STEVENSON, SH ;
MEREDITH, GR ;
RIKKEN, G ;
MARDER, SR .
JOURNAL OF PHYSICAL CHEMISTRY, 1991, 95 (26) :10631-10643
[5]   HYPER-RAYLEIGH SCATTERING IN SOLUTION [J].
CLAYS, K ;
PERSOONS, A .
PHYSICAL REVIEW LETTERS, 1991, 66 (23) :2980-2983
[6]  
DERHAEG L, 1991, ORGANIC MOL NONLINEA, P177
[7]   DESIGN OF CHROMOPHORIC MOLECULAR ASSEMBLIES WITH LARGE 2ND-ORDER OPTICAL NONLINEARITIES - A THEORETICAL-ANALYSIS OF THE ROLE OF INTERMOLECULAR INTERACTIONS [J].
DIBELLA, S ;
RATNER, MA ;
MARKS, TJ .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1992, 114 (14) :5842-5849
[8]   2ND-HARMONIC GENERATION IN POLED ORGANIC MONOMERIC GLASSES [J].
EICH, M ;
LOOSER, H ;
YOON, DY ;
TWIEG, R ;
BJORKLUND, G ;
BAUMERT, JC .
JOURNAL OF THE OPTICAL SOCIETY OF AMERICA B-OPTICAL PHYSICS, 1989, 6 (08) :1590-1597
[9]   THE 1,2-ALTERNATE CONFORMATION OF CALIX[4]ARENES - A RARE CONFORMATION - DYNAMIC H-1-NMR STUDIES OF FLEXIBLE TETRAALKYLATED CALIX[4]ARENES [J].
GROENEN, LC ;
VANLOON, JD ;
VERBOOM, W ;
HARKEMA, S ;
CASNATI, A ;
UNGARO, R ;
POCHINI, A ;
UGOZZOLI, F ;
REINHOUDT, DN .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1991, 113 (07) :2385-2392
[10]   SYN-1,2-DIALKYLATED CALIX[4]ARENES - GENERAL INTERMEDIATES IN THE NAH/DMF TETRAALKYLATION OF CALIX[4]ARENES [J].
GROENEN, LC ;
RUEL, BHM ;
CASNATI, A ;
TIMMERMAN, P ;
VERBOOM, W ;
HARKEMA, S ;
POCHINI, A ;
UNGARO, R ;
REINHOUDT, DN .
TETRAHEDRON LETTERS, 1991, 32 (23) :2675-2678
1234