HIGHLY ORDERED FILMS OF NEAT CALIX[4]ARENES FOR 2ND-ORDER NONLINEAR OPTICS

被引：41
作者：
KELDERMAN, E
HEESINK, GJT
DERHAEG, L
VERBIEST, T
KLAASE, PTA
VERBOOM, W
ENGBERSEN, JFJ
VANHULST, NF
CLAYS, K
PERSOONS, A
REINHOUDT, DN
机构：
[1] UNIV TWENTE,DEPT APPL PHYS,OPTOELECTR LAB,7500 AE ENSCHEDE,NETHERLANDS
[2] UNIV LEUVEN,DEPT CHEM,B-3001 LOUVAIN,BELGIUM
[3] TNO,PLAST & RUBBER RES INST,2600 JA DELFT,NETHERLANDS
来源：
ADVANCED MATERIALS | 1993年 / 5卷 / 12期
关键词：
D O I：
10.1002/adma.19930051211
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
In substituted calix[4]-arenes-cyclophanes consisting of four phenol moieties connected by methylene bridges-the number and also the relative positions of the donor and/or acceptor pi-conjugated (D-pi-A) units can be varied by changing the configuration. The Figure illustrates the cone configuration. The molecular and thin-film NLO properties of three tetra-D-pi-A-substituted calix[4]arenes, including their orientation in thin films and the stability of their NLO properties, are described.
引用
收藏
页码：925 / 930
页数：6
相关论文
共 31 条
  • [1] POLYMERS FOR NONLINEAR OPTICS
    BUCKLEY, A
    [J]. ADVANCED MATERIALS, 1992, 4 (03) : 153 - 158
  • [2] Chemla D. S., 1987, NONLINEAR OPTICAL PR, V1
  • [3] Chemla D.S., 1987, NONLINEAR OPTICAL PR, V2
  • [4] EXPERIMENTAL INVESTIGATIONS OF ORGANIC MOLECULAR NONLINEAR OPTICAL POLARIZABILITIES .1. METHODS AND RESULTS ON BENZENE AND STILBENE DERIVATIVES
    CHENG, LT
    TAM, W
    STEVENSON, SH
    MEREDITH, GR
    RIKKEN, G
    MARDER, SR
    [J]. JOURNAL OF PHYSICAL CHEMISTRY, 1991, 95 (26) : 10631 - 10643
  • [5] HYPER-RAYLEIGH SCATTERING IN SOLUTION
    CLAYS, K
    PERSOONS, A
    [J]. PHYSICAL REVIEW LETTERS, 1991, 66 (23) : 2980 - 2983
  • [6] DERHAEG L, 1991, ORGANIC MOL NONLINEA, P177
  • [7] DESIGN OF CHROMOPHORIC MOLECULAR ASSEMBLIES WITH LARGE 2ND-ORDER OPTICAL NONLINEARITIES - A THEORETICAL-ANALYSIS OF THE ROLE OF INTERMOLECULAR INTERACTIONS
    DIBELLA, S
    RATNER, MA
    MARKS, TJ
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1992, 114 (14) : 5842 - 5849
  • [8] 2ND-HARMONIC GENERATION IN POLED ORGANIC MONOMERIC GLASSES
    EICH, M
    LOOSER, H
    YOON, DY
    TWIEG, R
    BJORKLUND, G
    BAUMERT, JC
    [J]. JOURNAL OF THE OPTICAL SOCIETY OF AMERICA B-OPTICAL PHYSICS, 1989, 6 (08) : 1590 - 1597
  • [9] THE 1,2-ALTERNATE CONFORMATION OF CALIX[4]ARENES - A RARE CONFORMATION - DYNAMIC H-1-NMR STUDIES OF FLEXIBLE TETRAALKYLATED CALIX[4]ARENES
    GROENEN, LC
    VANLOON, JD
    VERBOOM, W
    HARKEMA, S
    CASNATI, A
    UNGARO, R
    POCHINI, A
    UGOZZOLI, F
    REINHOUDT, DN
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1991, 113 (07) : 2385 - 2392
  • [10] SYN-1,2-DIALKYLATED CALIX[4]ARENES - GENERAL INTERMEDIATES IN THE NAH/DMF TETRAALKYLATION OF CALIX[4]ARENES
    GROENEN, LC
    RUEL, BHM
    CASNATI, A
    TIMMERMAN, P
    VERBOOM, W
    HARKEMA, S
    POCHINI, A
    UNGARO, R
    REINHOUDT, DN
    [J]. TETRAHEDRON LETTERS, 1991, 32 (23) : 2675 - 2678
1234