CHIRAL DIETHANOLAMINES AND THEIR LITHIUM ALCOHOLATES AS CATALYSTS IN THE ENANTIOSELECTIVE ALKYLATION OF BENZALDEHYDE BY DIETHYLZINC

被引：9
作者：
DEVRIES, EFJ
BRUSSEE, J
KRUSE, CG
VANDERGEN, A
机构：
[1] LEIDEN UNIV,GORLAEUS LABS,DEPT CHEM,POB 9502,2300 RA LEIDEN,NETHERLANDS
[2] SOLVAY DUPHAR BV,1380 DA WEESP,NETHERLANDS
来源：
TETRAHEDRON-ASYMMETRY | 1993年 / 4卷 / 09期
关键词：
D O I：
10.1016/S0957-4166(00)82246-6
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The enantioselective alkylation of benzaldehyde by diethylzinc in the presence of catalytic amounts of bis-erythro diethanolamines and their lithium alcoholates was studied. The extent of asymmetric induction was found to depend strongly upon subtle changes in the structure of the catalyst used.
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页码：1987 / 1990
页数：4
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