A HIGHLY REGIOSELECTIVE REACTION OF N-FLUOROPYRIDINIUM SALTS WITH STABILIZED SULFUR, OXYGEN, AND NITROGEN NUCLEOPHILES - A CONVENIENT ROUTE TO 2-SUBSTITUTED PYRIDINES

被引：14

作者：

KISELYOV, AS

STREKOWSKI, L

机构：

[1] Department of Chemistry, Georgia State University, Atlanta, Georgia

来源：

JOURNAL OF HETEROCYCLIC CHEMISTRY | 1993年 / 30卷 / 05期

关键词：

D O I：

10.1002/jhet.5570300530

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

2-Substituted pyridines are efficiently obtained by the reactions of N-fluoropyridinium tetrafluoroborate or triflate with anions derived from benzenethiols, phenols, azoles, cyanamide, and with azide anion. The results are consistent with a nucleophile addition at the position 2 of the N-fluoropyridinium cation as the major reaction pathway.

引用

页码：1361 / 1364

页数：4

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