SANDWICHES, HALF-SANDWICHES AND RELATED F-ELEMENT ORGANOMETALLICS

被引:0
|
作者
STREITWIESER, A
BOUSSIE, TR
机构
来源
EUROPEAN JOURNAL OF SOLID STATE AND INORGANIC CHEMISTRY | 1991年 / 28卷
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中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
This survey of recent organo-f-element chemistry emphasizes the cyclooctatraene compounds of the f-elements that now include sandwich structures of central actinides in the +3 and +4 oxidation states and lanthanides of +2, +3, and +4, as well as half-sandwich structures of uranium(IV). A new application of a bis-cyclopentadienyllanthanide compound is as a catalyst for a Mukaiyama reaction of silyl enolates with aldehydes.
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页码:399 / 410
页数:12
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