THERMOLYTIC REACTIONS OF BENZOTRIAZINONE AND ISATOIC ANHYDRIDE

被引：49

作者：

CRABTREE, HE

SMALLEY, RK

SUSCHITZKY, H

机构：

[1] Department of Pure and Applied Chemistry, University of Salford, Salford

来源：

JOURNAL OF THE CHEMICAL SOCIETY C-ORGANIC | 1968年 / 22期

关键词：

D O I：

10.1039/j39680002730

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Benzotriazinone loses nitrogen on thermolysis in solution to give a heterodiene which reacts with dienophiles such as benzyne and p-methoxybenzaldehyde. Isatoic anhydride in hot solvents is attacked nucleophilically by esters with loss of carbon dioxide to give benzoxazinones.

引用

页码：2730 / +

页数：1

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