Crystal structure of (2E)-N-methyl-2-[(4oxo-4H-chromen-3-yl)methylidene]hydrazinecarbothioamide

被引：5

作者：

Vimala, G. ^{[1
]}

Govindaraj, J. ^{[2
]}

Haribabu, J. ^{[3
]}

Karvembu, R. ^{[3
]}

SubbiahPandi, A. ^{[1
]}

机构：

[1] Presidency Coll Autonomous, Dept Phys, Madras 600005, Tamil Nadu, India

[2] Pachaiyappas Coll Men, Dept Phys, Kancheepuram 631501, India

[3] Natl Inst Technol, Dept Chem, Tiruchirappalli 620015, India

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2014年 / 70卷

关键词：

crystal structure; hydrazinecarbothioamide; 4H-chromen-4one; biological properties; hydrogen bonding;

D O I：

10.1107/S1600536814021667

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

In the title compound, C12H11N3O2S, the dihedral angle between the 4H-chromen-4-one ring system and the -CH = N-NH-CS-NH- unit is 6.22 (1)degrees. In the crystal, inversion dimers linked by pairs of N-H center dot center dot center dot O hydrogen bonds generate R-2(2) (14) loops. The dimers are reinforced by a pair of C-H center dot center dot center dot O interactions, which generate R-2(2)(10) loops.

引用

页码：O1151 / +

页数：7

共 50 条

[1] Crystal structures of two hydrazinecarbothioamide derivatives: (E)-N-ethyl-2-[(4-oxo-4H-chromen-3-yl)methylidene]hydrazinecarbothioamide hemihydrate and (E)-2-[(4-chloro-2H-chromen-3-yl)methylidene]-N-phenylhydrazinecarbothioamide
Gangadharan, Rajeswari
Haribabu, Jebiti
Karvembu, Ramasamy
Sethusankar, K.
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2015, 71 : 305 - +
[2] (E)-4-Methyl-N'-[(4-oxo-4H-chromen-3-yl)methylidene]benzohydrazide
Ishikawa, Yoshinobu
Watanabe, Kohzoh
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2014, 70 : O565 - +
[3] Crystal structure of (2E)-N-methyl-2-(2-oxo-1,2-dihydroacenaphthylen-1- ylidene) hydrazinecarbothioamide
Vimala, G.
Govindaraj, J.
Haribabu, J.
Karvembu, R.
SubbiahPandi, A.
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2014, 70 : 415 - +
[4] Crystal structure of (E)-2-[(4-chloro-2H-chromen-3-yl) methylidene]-N-cyclohexylhydrazinecarbothioamide
Gangadharan, Rajeswari
Haribabu, Jebiti
Karvembu, Ramasamy
Sethusankar, K.
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2014, 70 : O1039 - +
[5] (2E)-N-Methyl-2-[(2E)-3-phenylprop-2-en-1-ylidene]hydrazinecarbothioamide
Krishna, P. Murali
Anilkumar, G. N.
Reddy, K. Hussain
Kokila, M. K.
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2012, 68 : O2842 - +
[6] Crystal structure of 4-methyl-2-oxo-2H-chromen-7-yl ferrocenecarboxylate
Yu, Juan
Gao, Lei-Lei
Huang, Peng
Wang, Dian-Lei
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2014, 70 : M369 - +
[7] Crystal structure of the triethylammonium salt of 3-[(4-hydroxy-3-methoxyphenyl)(4-hydroxy-2-oxo-2H-chromen-3-yl)methyl]-2-oxo-2H-chromen-4-olate
Ikram, Muhammad
Rehman, Sadia
Khan, Afzal
Schulzke, Carola
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2018, 74 : 282 - +
[8] Crystal structure of (7-chloro-2-oxo-2H-chromen-4-yl)methyl N,N-dimethyl-carbamodithioate
Kavitha, H. D.
Vinduvahini, M.
Mahabhaleshwaraiah, N. M.
Kotresh, O.
Devarajegowda, H. C.
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2015, 71 : O263 - U414
[9] Molecular structure, NBO analysis of the hydrogen-bonded interactions, spectroscopic (FT-IR, FT-Raman), drug likeness and molecular docking of the novel anti COVID-2 molecule (2E)-N-methyl-2-[(4-oxo-4H-chromen-3-yl)methylidene]-hydrazinecarbothioamide (Dimer) - quantum chemical approach
Mary, S. J. Jenepha
Pradhan, Sayantan
James, C.
SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY, 2021, 251
[10] Crystal structure of (6-bromo-2-oxo-2H-chromen-4-yl)methyl morpholine-4-carbodithioate
Kumar, K. Mahesh
Roopashree, K. R.
Vinduvahini, M.
Kotresh, O.
Devarajegowda, H. C.
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2015, 71 : O489 - U349

← 1 2 3 4 5 →