CARBORANYLHALONIUM IONS - FROM STRIKING REACTIVITY TO A UNIFIED MECHANISTIC ANALYSIS OF POLAR REACTIONS OF DIARYLHALONIUM COMPOUNDS

被引:87
作者
GRUSHIN, VV [1 ]
机构
[1] USSR ACAD SCI,INST ORGANO ELEMENT CPDS,28 VAVILOVA,MOSCOW,USSR
关键词
D O I
10.1021/ar00023a007
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
In 1894 Hartmann and Meyer reported the preparation of the first halonium compound, (4-iodophenyl) phenyliodonium hydrogen sulfate.1 Since that time hundreds of aromatic, aliphatic, and heterocyclic iodonium, bromonium, and chloronium ions have been synthesized and investigated.2, 4 However, neither inorganic nor organometallic halonium ions were known before we started investigations described in the present Account.6. © 1992, American Chemical Society. All rights reserved.
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页码:529 / 536
页数:8
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